Abstract
Alkenyl(amino)carbene chromium(0) complexes 1 undergo regioselective [6 + 3] cycloaddition to pentafulvenes 2, affording substituted dihydroindenes 5a– d and indene 6. In the case of 6,6-dimethylpentafulvene 2a dihydroindene chromium complexes 4a– c were also isolated. Isopropylfulvene 2b similarly produces 5d or, under oxidative reaction conditions, the indene 6. The reaction involves: (i) 1,2-nucleophilic addition of fulvene to the carbene carbon, (ii) [1,2]-Cr(CO) 5 migration, (iii) either metal–indene coordination or reductive metal elimination/aromatization.
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