Abstract
Reaction between [(C2H4)2RhCl]2 and the 2,3-dihydro-1.3-diborole derivative 1 yields [(l)RhCl]2 (3). In 3 the chloro-bridge can be replaced by the 2,3-dihydro-l,3-diborolyl(1-H) or by the cyclopentadienyl group to give the sandwich complexes 4 and 5, respectively. The complexes 3-5 contain a penta-coordinated carbon atom in the ligand 1. 1H and 11B NMR data are reported.
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