Abstract
The title compound, C15H14F2N2O3, was obtained in a one-pot three-component reaction from 4-(difluoromethoxy)benzaldehyde, cyclohexane-1,3-dione and urea, with a catalytic amount of p-toluenesulfonic acid. The 4-(difluoromethoxy)phenyl ring is positioned axially, perpendicular to, and bisecting the six-membered heterocyclic ring. The heterocyclic ring adopts a puckered boat conformation, whereas the cyclohexene ring is in a half-chair conformation. The molecules are linked by N—H⋯O, C—H⋯O, N—H⋯F and C—H⋯F intermolecular hydrogen bonds.
Published Version
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