Abstract
In the crystal of the title compound, C13H12ClNO2S, the N—H bond is anti to the meta-methyl group in the aniline ring. The C—SO2—NH—C torsion angle is −57.6 (2)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 84.7 (1)°. The crystal structure features inversion-related dimers linked by pairs of N—H⋯O hydrogen bonds.
Highlights
In the crystal of the title compound, C13H12ClNO2S, the N—H bond is anti to the meta-methyl group in the aniline ring
The N—H bond is anti to the meta-methyl group in the anilino ring, similar to that observed in 4-methyl-N-(3-methylphenyl)-benzenesulfonamide (II) (Nirmala et al, 2009), but in contrast to the syn conformation observed with respect to the meta-methyl groups in N-(3-methylphenyl)-benzenesulfonamide (III) (Gowda et al, 2010)
The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry
Summary
H atoms treated by a mixture of independent and constrained refinement max = 0.44 e Å3. R factor = 0.043; wR factor = 0.119; data-to-parameter ratio = 16.6. In the crystal of the title compound, C13H12ClNO2S, the N—H bond is anti to the meta-methyl group in the aniline ring. The. C—SO2—NH—C torsion angle is 57.6 (2). The sulfonyl and aniline benzene rings are tilted relative to each other by. The crystal structure features inversion-related dimers linked by pairs of N—H O hydrogen bonds
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
