Abstract
In the title compound, C15H14ClNO, the ortho- and meta-methyl substituents in the aniline ring are anti to the N—H bond. The dihedral angle between the benzoyl and aniline benzene rings is 95.0 (1)°. N—H⋯O hydrogen bonds and C—H⋯π interactions link the molecules in the crystal structure.
Highlights
C15H14ClNO, the ortho- and metamethyl substituents in the aniline ring are anti to the N—H bond
Absorption correction: analytical [CrysAlis RED (Oxford Diffraction, 2009), based on expressions derived by Clark &
Symmetry codes: (i) x, −y+3/2, z+1/2; (ii) x+1, y, z
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.003 A; R factor = 0.049; wR factor = 0.145; data-to-parameter ratio = 16.9. C15H14ClNO, the ortho- and metamethyl substituents in the aniline ring are anti to the N—H bond. N—HÁ Á ÁO hydrogen bonds and C— HÁ Á Á interactions link the molecules in the crystal structure. For our studies on the effects of substituents on the structures and other aspects of N-(aryl)-amides, see: Bowes et al (2003); Gowda et al (2001); Rodrigues et al (2011), on N-(aryl)-methanesulfonamides, see: Jayalakshmi & Gowda (2004), on N-(aryl)-arylsulfonamides, see: Gowda et al (2005) and on N-chloroarylamides, see: Gowda et al (1996)
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