{4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}copper(II)

Hadi Kargar,Saeideh Abbasian,Reza Kia,Muhammad Nawaz Tahir

doi:10.1107/s160053681200195x

Abstract

In the title Schiff base complex, [Cu(C19H16Cl4N2O2)], the geometry around the CuII atom is distorted square-planar defined by the N2O2 donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 29.95 (16)°. In the crystal, molecules are linked along the b axis, forming individual dimers through C—H⋯O interactions. The crystal structure is further stabilized by intermolecular π–π interactions [centroid–centroid distance = 3.6131 (17) Å].

Highlights

In the title Schiff base complex, [Cu(C19H16Cl4N2O2)], the geometry around the CuII atom is distorted square-planar defined by the N2O2 donor atoms of the coordinated ligand
Molecules are linked along the b axis, forming individual dimers through C—H O interactions
The crystal structure is further stabilized by intermolecular – interactions [centroid–centroid distance =

Summary

Crystal data

R. of IRAN, bX-ray Crystallography Lab., Plasma Physics Research Center, Science and Research Branch, Islamic Azad University, Tehran, Iran, cDepartment of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran, and d

Data collection

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