{4,4′,6,6′-Tetrachloro-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]}nickel(II)

Hadi Kargar,Saeideh Abbasian,Reza Kia,Muhammad Nawaz Tahir

doi:10.1107/s1600536812002085

Abstract

In the title compound, [Ni(C19H16Cl4N2O2)], the NiII ion is in a distorted square-planar environment coordinated by two N atoms and two O atoms of the tetradentate ligand. The dihedral angle between the benzene rings is 24.8 (2)°. In the crystal, molecules are linked into chains along the b axis by weak C—H⋯O and C—H⋯Cl interactions. An intermolecular Cl⋯Cl [3.4564 (19) Å] interaction is present which is shorter than the sum of the van der Waals radii of Cl atoms (3.50 Å).

Highlights

Crystal dataR. of IRAN, bX-ray Crystallography Lab., Plasma Physics Research Center, Science and Research Branch, Islamic Azad University, Tehran, Iran, cDepartment of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran, and d
In the title compound, [Ni(C19H16Cl4N2O2)], the Ni ion is in a distorted square-planar environment coordinated by two N
Molecules are linked into chains along the b axis by weak C—H O and C—H Cl interactions

Summary

Crystal data

R. of IRAN, bX-ray Crystallography Lab., Plasma Physics Research Center, Science and Research Branch, Islamic Azad University, Tehran, Iran, cDepartment of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran, and d

Data collection

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