3D microstructure characterization of 2D Cf-ZrB2-SiC ultra-high temperature ceramic matrix composites using X-ray microscopy

Abstract

A study has been carried out to examine the impact of fibre architecture on the infiltration permeability, constituent phase volume fractions, and matrix porosity of the carbon fibre (Cf)-ZrB2-20 vol% SiC ceramic matrix composites prepared through slurry infiltration, followed by hand lay-up and hot pressing. Unidirectional (UD) Cf-fibres in 0/0° and 0/90° orientations, as well as 8H satin woven Cf-fibres, have been utilized as reinforcement in the composites, which were subsequently densified through hot pressing after infiltration. Revelation of the 3D internal structure of the composites by X-ray microscopy has facilitated a thorough qualitative and quantitative evaluation of infiltration. The fraction of matrix (ZrB2 - 20 vol% SiC) present along three orthogonal axes (X, Y and Z) of the scanned composite blocks has been calculated, with Z representing the direction of infiltration. This study has revealed that the composites processed from UD Cf-fibre preform exhibits greater infiltration, because of higher intra-bundle infiltration compared to the 8H woven Cf-fibre, and the accompanying analysis provides insight into the formation mechanisms of matrix porosities.