Abstract
The title compound, [Ru3(C12H12N)3(CO3)(C6H6)3]PF6·CH2Cl2, was obtained unintentionally as the product of an attempted deprotonation of the monomeric parent ruthenium complex [Ru(C12H12N)(C6H6)(C2H3N)]PF6. The carbonate ligand bridges three half-sandwich cycloruthenated fragments, each of them exhibiting a pseudo-tetrahedral geometry. The configuration of the Ru atoms is S. The naphthyl groups of the enantiopure cycloruthenated benzylic amine ligands point in the same direction, adopting a propeller shape.
Highlights
[Ru3(C12H12N)3(CO3)(C6H6)3]PF6CH2Cl2, was obtained unintentionally as the product of an attempted deprotonation of the monomeric parent ruthenium complex [Ru(C12H12N)(C6H6)(C2H3N)]PF6
The naphthyl groups of the enantiopure cycloruthenated benzylic amine ligands point in the same direction, adopting a propeller shape
The authors are indebted to the Ministère de l’Education Nationale for a fellowship granted to JBS
Summary
L3-Carbonato-j3O:O0 :O0 0 -tris{(g6benzene)[(R)-1-(1-aminoethyl)naphthylj2C2,N]ruthenium(II)} hexafluoridophosphate dichloromethane solvate. Institut de Chimie de Strasbourg, Université Louis Pasteur, Laboratoire de Synthèses. Métallo-Induites, UMR 7177 CNRS, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France, and bInstitut de Chimie de Strasbourg, Université Louis Pasteur, Service de Radiocristallographie, UMR 7177 CNRS, 4 rue Blaise Pascal, 67070 Strasbourg. R factor = 0.053; wR factor = 0.132; data-to-parameter ratio = 19.1
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