The first complex of the pentameric phosphazane macrocycle [{P(μ-N tBu)} 2(μ-NH)] 5 with a neutral molecular guest: Synthesis and structure of [{P(μ-N tBu)} 2(μ-NH)] 5(CH 2Cl 2) 2

Abstract

The reaction of [{P(μ-N t Bu)} 2(μ-NH)} 5I] −[Li(thf) 4] +([ 1 · I] −[Li(thf) 4] +) with NaOMe in CH 2Cl 2 gives the title compound [{P(μ-N t Bu)} 2(μ-NH)] 5(CH 2Cl 2) 2 [ 1 · (CH 2Cl 2) 2] the first adduct containing this type of macrocyclic phosph(III)azane host and a neutral guest.