(3,6-Dimethyl-1,2,4,5-tetrazine-1,4-diyl)bis[(morpholin-4-yl)methanone

Na-Bo Sun,Yan-Mei Guo,Guo-Wu Rao

doi:10.1107/s1600536812004849

Abstract

In the title molecule, C14H22N6O4, the amide-substituted N atoms of the tetrazine ring deviate from the approximate plane of the four other atoms in the ring by 0.160 (2) and 0.243 (2) Å, forming a slight boat conformation. The morpholine rings are in chair conformations.

Highlights

In the title molecule, C14H22N6O4, the amide-substituted N atoms of the tetrazine ring deviate from the approximate plane of the four other atoms in the ring by 0.160 (2) and
The title compound was the product of the reaction of bis(trichloromethyl) carbonate, morpholine, and 3,6-dimethyl-1,6dihydro-1,2,4,5-tetrazine according to the procedure (Hu et al, 2004; Sun et al, 2003; Skorianetz & Kováts, 1970, 1971)
The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry

Summary

Bruker SMART CCD diffractometer

College of Biology and Environmental Engineering, Zhejiang Shuren University, Hangzhou 310015, People’s Republic of China, and bCollege of Pharmaceutical. Zhejiang University of Technology, Hangzhou 310014, People’s Republic of China. R factor = 0.049; wR factor = 0.142; data-to-parameter ratio = 16.9. C14H22N6O4, the amide-substituted N atoms of the tetrazine ring deviate from the approximate plane of the four other atoms in the ring by 0.160 (2) and. 0.243 (2) Å, forming a slight boat conformation. The morpholine rings are in chair conformations. Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999)

The authors are very grateful to the National Natural

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