Abstract
In the title complex, [Cu(C16H11Cl2NO4)(C3H7NO)] , the CuII atom is coordinated by two O atoms and one N atom from the tridentate ligand L 2− {LH2 = (2S)-[2-(3,5-dichloro-2-hydroxybenzylidene)imino]-3-(4-hydroxyphenyl)propionic acid} and one O atom from a dimethylformamide molecule, resulting in a slightly distorted square-planar geometry. The structure forms a one-dimensional chain through weak coordination bonds [Cu⋯O 3.080 (1), Cu⋯Cl 3.269 (1) Å] and a three-dimensional network through O—H⋯O and C—H⋯O hydrogen bonds.
Highlights
In the title complex, [Cu(C16H11Cl2NO4)(C3H7NO)], the CuII atom is coordinated by two O atoms and one N atom from the tridentate ligand L2À {LH2 = (2S)-[2-(3,5-dichloro-2-hydroxybenzylidene)imino]-3-(4-hydroxyphenyl)propionic acid} and one O atom from a dimethylformamide molecule, resulting in a slightly distorted square-planar geometry
The structure forms a one-dimensional chain through weak coordination bonds [CuÁ Á ÁO 3.080 (1), CuÁ Á ÁCl 3.269 (1) A ] and a threedimensional network through O—HÁ Á ÁO and C—HÁ Á ÁO hydrogen bonds
Symmetry codes: (i) −x+1, y+1/2, −z+3/2; (ii) x+1/2, −y−1/2, −z+2
Summary
The structure forms a one-dimensional chain through weak coordination bonds [CuÁ Á ÁO 3.080 (1), CuÁ Á ÁCl 3.269 (1) A ] and a threedimensional network through O—HÁ Á ÁO and C—HÁ Á ÁO hydrogen bonds
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