Abstract
A new ionic complex [Ni(meso-cth)][Cr(ox)2(bpy)](H2O)(ClO4) [meso-cth = meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, ox = oxalato ainon, bpy = 2,2′-bipyridine] was prepared and its structure was determined. The complex was found to crystallized in monoclinic space group P2(1)/n, with a = 13.6000(4) A, b = 18.763(5) A, c = 14.995(4) A, β =106.958(5)°, V = 3659.9(17) A3, and Z = 4. The structure consisted of cationic [Ni(meso-cth)]2+, anionic [Cr(ox)2(bpy)]−, and perchlorate anions; the cationic [Ni(meso-cth)]2+ and anionic [Cr(ox)2(bpy)]− units were related by weak coordination bonds and hydrogen bonds.
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