Abstract
Ordering phenomena: The “reactive” adsorption and lateral ordering of redox-active dibenzyl viologens (DBV) on a chloride-modified Cu(100) electrode surface is studied. At electrode potentials where the first electron transfer step from the di-cationic to the radical mono-cationic viologen takes place, the preferred products at the surface are metastable viologen dimer species (see STM images).
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