Abstract

The title compound, C13H16O, comprises two fused five-membered rings. Each ring has an envelope conformation, with the ether O atom in the furan­ose ring, and the CMe2 atom in the acetonide ring as the flap atoms. In the crystal, centrosymmetrically related mol­ecules associate via hydr­oxy–ether O—H⋯O hydrogen bonds and the resulting dimers are linked into a supra­molecular chain with a flattened topology via C—H⋯Ohydr­oxy contacts, and aligned in the a-axis direction.

Highlights

  • The title compound, C13H16O, comprises two fused fivemembered rings

  • Centrosymmetrically related molecules associate via hydroxy

  • Ether O—H O hydrogen bonds and the resulting dimers are linked into a supramolecular chain with a flattened topology via C—H Ohydroxy contacts, and aligned in the a-axis direction

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Summary

Data collection

T. Discipline of Chemistry, University of Adelaide, 5005 South Australia, Australia, b. Discipline of Wine and Horticulture, University of Adelaide, Waite Campus, Glen, Osmond 5064, South Australia, Australia, and cDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia. R factor = 0.045; wR factor = 0.157; data-to-parameter ratio = 15.3. The title compound, C13H16O, comprises two fused fivemembered rings. Each ring has an envelope conformation, with the ether O atom in the furanose ring, and the CMe2 atom in the acetonide ring as the flap atoms. Ether O—H O hydrogen bonds and the resulting dimers are linked into a supramolecular chain with a flattened topology via C—H Ohydroxy contacts, and aligned in the a-axis direction

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