Abstract
In the title compound, [Cu(C6H5O3)(C18H15P)2]·C18H15P·CH3OH, the pyran-4-one ring is appromimately planar (r.m.s deviation = 0.0138 Å), with the CuI atom 0.451 (5) Å out of the plane. The CuI atom has a distorted tetrahedral coordination. The O—Cu—O angle is 80.07 (8)° and the P—Cu—P angle is 123.49 (3)°. The crystal packing is stablized by intramolecular C—H⋯O interactions and intermolecular C—H⋯O and O—H⋯O interactions.
Highlights
Structure ReportsR factor = 0.049; wR factor = 0.127; data-to-parameter ratio = 17.3
The crystal packing is stablized by intramolecular C—H O interactions and intermolecular C—
The title compound is structurally related to the flavonolato, nitrosophenylhydroxylaminato and tropolonato derivatives, see: Spier et al (1990); Charalambous et al (1984); Steyl
Summary
R factor = 0.049; wR factor = 0.127; data-to-parameter ratio = 17.3. In the title compound, [Cu(C6H5O3)(C18H15P)2]C18H15PCH3OH, the pyran-4-one ring is appromimately planar (r.m.s deviation = 0.0138 Å), with the CuI atom 0.451 (5) Å out of the plane. The CuI atom has a distorted tetrahedral coordination. The O—Cu—O angle is 80.07 (8) and the P—. The crystal packing is stablized by intramolecular C—H O interactions and intermolecular C—.
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