Catena-Poly[[[(pyridine-κN)copper(II)]-μ-3-{1-[(2-aminoethyl)imino]ethyl}-6-methyl-2-oxo-2H-pyran-4-olato-κ4N,N,O4:O2] perchlorate

Abstract

In the title compound, {[Cu(C10H13N2O3)(C5H5N)]ClO4}n, the CuII atom has an N3O2 coordination sphere. The complex contains two different ligands, viz. a pyridine mol­ecule and a Schiff base mol­ecule, resulting from the condensation of ethyl­enodiamine with dehydro­acetic acid. The CuII atom exhibits a square-pyramidal geometry: three of the four donors of the pyramid base belong to the Schiff base ligand (an N atom from the amine group, a second N atom from the imine group and the O atom of the pyran­one residue) and the fourth donor is the pyridine N atom. The coordination around the metal ion is completed by a longer axial bond to the pyran­one O atom of an adjacent Schiff base, so forming a one-dimensional polymer. The complex has a +1 charge that is compensated by a perchlorate ion. The crystal packing, which can be described as alternating chains of cations and tetra­hedral perchlorate anions along the a axis, is stabilized by inter­molecular N—H⋯O, C—H⋯O and C—H⋯N hydrogen-bonding interactions.