Abstract
In the title compound, (C12H12NO2)[Sn(C4H9)(C10H6NO2)Cl3], the Sn atom is coordinated by one O and one N atom of a quinolinium-2-carboxylate anion, three Cl atoms and one butyl ligand within a distorted octahedron. Three C atoms of the butyl ligand are disordered and were refined using a split model; the site occupancies are 0.57 and 0.43. The NH group of the cation is involved in intermolecular N—H⋯O hydrogen bonding.
Highlights
In the title compound, (C12H12NO2)[Sn(C4H9)(C10H6NO2)Cl3], the Sn atom is coordinated by one O and one N atom of a quinolinium-2-carboxylate anion, three Cl atoms and one butyl ligand within a distorted octahedron
The NH group of the cation is involved in intermolecular N—HÁ Á ÁO hydrogen bonding
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: NC2083)
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.010 A; disorder in main residue; R factor = 0.045; wR factor = 0.132; data-to-parameter ratio = 15.1. In the title compound, (C12H12NO2)[Sn(C4H9)(C10H6NO2)Cl3], the Sn atom is coordinated by one O and one N atom of a quinolinium-2-carboxylate anion, three Cl atoms and one butyl ligand within a distorted octahedron. Three C atoms of the butyl ligand are disordered and were refined using a split model; the site occupancies are 0.57 and 0.43. The NH group of the cation is involved in intermolecular N—HÁ Á ÁO hydrogen bonding
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