Abstract
In the title polymeric coordination compound, [Sn(CH3)2(C2H2ClO2)Cl]n, the Sn atom has a distorted trigonal–bipyramidal geometry, with two O atoms of the ligands in axial positions and two methyl groups and one Cl atom in equatorial positions. Adjacent Sn atoms are bridged by the two O atoms of the carboxylate ligand, forming a chain structure along the a-axis direction.
Highlights
In the title polymeric coordination compound, [Sn(CH3)2(C2H2ClO2)Cl]n, the Sn atom has a distorted trigonal– bipyramidal geometry, with two O atoms of the ligands in axial positions and two methyl groups and one Cl atom in equatorial positions
Adjacent Sn atoms are bridged by the two O atoms of the carboxylate ligand, forming a chain structure along the a-axis direction
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: KP2369)
Summary
Key indicators: single-crystal X-ray study; T = 298 K; mean (C–C) = 0.010 A; R factor = 0.040; wR factor = 0.100; data-to-parameter ratio = 18.2. In the title polymeric coordination compound, [Sn(CH3)2(C2H2ClO2)Cl]n, the Sn atom has a distorted trigonal– bipyramidal geometry, with two O atoms of the ligands in axial positions and two methyl groups and one Cl atom in equatorial positions. Adjacent Sn atoms are bridged by the two O atoms of the carboxylate ligand, forming a chain structure along the a-axis direction. Related literature For the biological activity of organotin compounds, see: Dubey & Roy (2003). See: Wang et al (2007); Ma et al (2008). Monoclinic, P21=c a = 6.988 (3) Ab = 9.948 (4) Ac = 12.686 (6) A = 98.891 (5) V = 871.3 (7) A 3
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