Abstract
In the title compound, C14H12ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C=O bond. The benzoyl and aniline benzene rings are tilted relative to each other by 82.8 (1)°. In the crystal, intermolecular N—H⋯O hydrogen bonds link the molecules into infinite chains running along the c-axis direction.
Highlights
In the title compound, C14H12ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C O bond
Intermolecular N—HÁ Á ÁO hydrogen bonds link the molecules into infinite chains running along the c-axis direction
Absorption correction: analytical [CrysAlis RED (Oxford Diffraction, 2009), based on expressions derived from Clark &
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.004 A; R factor = 0.057; wR factor = 0.138; data-to-parameter ratio = 23.3. C14H12ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C O bond. The benzoyl and aniline benzene rings are tilted relative to each other by 82.8 (1). Intermolecular N—HÁ Á ÁO hydrogen bonds link the molecules into infinite chains running along the c-axis direction. Related literature For the preparation of the title compound, see: Gowda et al (2003). For studies on the effects of substituents on the structures and other aspects of N-(aryl)-amides, see: Bowes et al (2003); Gowda et al (2000); Saeed et al (2010), on N-(aryl)methanesulfonamides, see: Gowda et al (2007), on N-(aryl)arylsulfonamides, see: Shetty & Gowda (2005) and on Nchloro-arylsulfonamides, see: Gowda & Shetty (2004)
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