Abstract

The interaction of a series of acrylic and cinnamic acid amides with bis(pentafluorophenyl)-phosphinic acid proceeds vigorously at room temperature without any catalyst in the presence of the organic solvents providing for a high fraction of the >P–OH tautomer of the phosphinic acid. The reactions have afforded (2-carbamoylethyl)bis(pentafluorophenyl)phosphine oxides in a high yield.

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