Abstract
The bis(anilino)phosphine oxide (PhNH)2P(O)H as a ligand reacts directly with zirconocene dichloride CP2ZrCl2 to afford H(PhNH)P[(NPh)OZr(Cp)2Cl] (1), while in the presence of triethylamine as a base the ligand is deprotonated and H(O)P[(NPh)2Zr(Cp)2] (2) is isolated in a very good yield. When the ligand is treated with TiCl4, however, the diligand complex Cl3TiO(NPh)PH(NPh)PHO(Nph)TiCl3 (3) is separated in high yield. These new compounds have been fully characterized by FT-IR, UV–Vis spectrophotometry and multi-nuclear (1H, 31P) NMR spectroscopy and elemental analysis as well as XRF analysis of SEM images.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
