Abstract

The title 1:1 adduct, C5H5BrN2·C7H6O3, contains two mol­ecules of each species in the asymmetric unit, with similar geometries. In the crystal, mol­ecules are linked to form extended chains along [100] by N—H⋯O, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds. Adjacent chains are crosslinked via further N—H⋯O inter­actions into sheets lying parallel to (001). The crystal studied was an inversion twin with a 0.54 (2):0.46 (2) domain ratio.

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