Abstract
In the title compound, C46H50O12·2CH2Cl2, each dual 20-crown-6 unit crystallizes with two dichloromethane solvent molecules. The crown unit molecule lies about an inversion centre located at the central benzene ring. The two crown ring groups adopt an anti conformation, stabilized by weak intramolecular C—H⋯O interactions. In the crystal, the crown unit molecules and the solvent molecules are linked by C—H⋯O interactions into a three-dimensional network.
Highlights
C46H50O122CH2Cl2, each dual 20crown-6 unit crystallizes with two dichloromethane solvent molecules
The crown unit molecule lies about an inversion centre located at the central benzene ring
In a previous article we reported the synthesis and complexation behavior of common-nuclear bis-crown ethers (Lee et al, 1992, 1997)
Summary
R factor = 0.051; wR factor = 0.136; data-to-parameter ratio = 14.6. C46H50O122CH2Cl2, each dual 20crown-6 unit crystallizes with two dichloromethane solvent molecules. The crown unit molecule lies about an inversion centre located at the central benzene ring. The two crown ring groups adopt an anti conformation, stabilized by weak intramolecular C—H O interactions. The crown unit molecules and the solvent molecules are linked by. C—H O interactions into a three-dimensional network
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