Abstract
In the title compound, C51H45N9O3, three 1-(1H-benzotriazol-1-ylmethyl)-3-phenyloxy (bmph) ligands are bonded to the central benzene ring in an asymmetric arrangement, two bmph located on one side of the central benzene ring and the other bmph located on the opposite side of the central benzene ring. The dihedral angles between the central benzene ring and the three pendant phenoxy rings are 76.71 (14), 67.81 (13) and 70.67 (16)°. In the crystal structure, one bmph is disordered over two sites in a 0.611 (5):0.389 (5) ratio. Some of the methyl H atoms are equally disordered over two sets of sites. Intermolecular C—H⋯N hydrogen bonding is present in the crystal structure.
Highlights
C51H45N9O3, three 1-(1H-benzotriazol1-ylmethyl)-3-phenyloxy ligands are bonded to the central benzene ring in an asymmetric arrangement, two bmph located on one side of the central benzene ring and the other bmph located on the opposite side of the central benzene ring
The dihedral angles between the central benzene ring and the three pendant phenoxy rings are 76.71 (14), 67.81 (13) and
IN the crystal structure the three 1-(1Hbenzotriazol-1-ylmethyl)-3-phenyloxy groups are bonded to the central benzene ring with an asymmetric arrangement, two bmph located on one side of the central benzene ring and the other bmph located on the opposite side of the central benzene ring
Summary
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, People’s Republic of China, and bDepartment of Chemistry, Henan. Key indicators: single-crystal X-ray study; T = 295 K; mean (C–C) = 0.005 Å; disorder in main residue; R factor = 0.058; wR factor = 0.187; data-to-parameter ratio = 14.4. C51H45N9O3, three 1-(1H-benzotriazol1-ylmethyl)-3-phenyloxy (bmph) ligands are bonded to the central benzene ring in an asymmetric arrangement, two bmph located on one side of the central benzene ring and the other bmph located on the opposite side of the central benzene ring. One bmph is disordered over two sites in a 0.611 (5):0.389 (5) ratio. H atoms are disordered over two sets of sites. Intermolecular C—H N hydrogen bonding is present in the crystal structure
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