Abstract

The two title calix[4]arene compounds, C34H32O8, (I), and C36H36O8*CH3Cl, (II), respectively, which differ only in the size of the alkyl function on the pendant ester group, are compared. Compound (I) forms a novel supramolecular array, whilst (II) fails to do so due to accommodating a chloroform guest molecule in the lower-rim cavity.

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