Abstract
An efficient process for the conversion of glucose into 5-hydroxymethylfurfural (HMF) with environmentally friendly and cheap catalysts was studied in the ionic liquid 1-butyl-3-methylimidazolium chloride ([BMIM]Cl). Among the catalysts employed, the combination of 12-tungstophosphoric acid (12-TPA)/boric acid (B(OH)3) in the experiments resulted in the highest yield of HMF. The effects of various reaction parameters on HMF yields were also investigated. An HMF yield of 51.9% was achieved at 140 °C for 40 min. In addition, a small amount of water in this reaction system had little effect on the HMF yields. After the extraction of HMF, [BMIM]Cl and 12-TPA/B(OH)3 could be reused and exhibited stable activities after five successive runs. More interestingly, like [BMIM]Cl, tetraethyl ammonium chloride (TEAC) could be favorable to HMF formation and was also used as an effective solvent for the conversion of glucose into HMF.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
