Abstract
This chapter describes the latest advances in the investigation of the optical properties of roll-to-roll (r2r) printed nanolayers for flexible organic electronics applications, as organic photovoltaics, by in-line spectroscopic ellipsometry (SE) in the visible–far ultraviolet spectral region. First, it focuses on the fundamentals of SE as well as on the aspects for its adaptation on r2r systems. Afterward, it reports on the results from the robust in-line determination and quality control of thickness and optical properties of polymer organic semiconductors, poly(3,4-ethylenedioxy-thiophene):poly(styrene-sulfonate) transparent electrodes and high barrier nanomaterials deposited onto flexible polymer substrates in the form of rolls.
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