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https://doi.org/10.1002/anie.198603351
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Cite Publication Date: Apr 1, 1986 | |
 Citations: 11 |
Affiliation: Heidelberg University, University of Basel
The title compound 1 is a record olefin in more ways than one. Not only the four α-but also the two β-spirocyclopropane groups exert a donor effect on the double bond. The π-ionization potential of 7.3 eV and the oxidation potential of 0.74 V are the lowest values observed so far for monoolefins without heteroatom donor substituents.
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