Abstract
In the title compound, C25H26ClN, the piperidine ring has a chair conformation with all ring substituents in equatorial positions. The dihedral angle formed between the chlorobenzene ring and the flanking phenyl rings are 74.91 (18) and 47.86 (17)°. The chloro substituent is anti to the piperidine N atom. In the crystal, centrosymmetrically related molecules aggregate via π–π interactions occurring between chlorobenzene rings [centroid–centroid distance = 3.778 (2) Å] and these are linked into linear supramolecular chains along the a axis by C—H⋯π interactions occurring between the phenyl rings.
Highlights
In the title compound, C25H26ClN, the piperidine ring has a chair conformation with all ring substituents in equatorial positions
The dihedral angle formed between the chlorobenzene ring and the flanking phenyl rings are 74.91 (18) and
Centrosymmetrically related molecules aggregate via – interactions occurring between chlorobenzene rings [centroid–centroid distance = 3.778 (2) Å] and these are linked into linear supramolecular chains along the a axis by C—H interactions occurring between the phenyl rings
Summary
Tmin = 0.495, Tmax = 1.000 a Centre for Nanotechnology, Department of Chemistry, Kalasalingam University, Krishnankoil 626 126, Tamilnadu, India, bDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia, and cChemistry Department and Faculty of Science, King Abdulaziz University, PO Box 80203 Jeddah, Saudi Arabia. C25H26ClN, the piperidine ring has a chair conformation with all ring substituents in equatorial positions. The dihedral angle formed between the chlorobenzene ring and the flanking phenyl rings are 74.91 (18) and. The chloro substituent is anti to the piperidine N atom. Centrosymmetrically related molecules aggregate via – interactions occurring between chlorobenzene rings [centroid–centroid distance = 3.778 (2) Å] and these are linked into linear supramolecular chains along the a axis by C—H interactions occurring between the phenyl rings
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