1,2-Bis(2-pyridylmethoxy)benzene-κ4N,O,O′,N′]bis(nitrato-κO)copper(II)

Ying-Hui Yu,Jin-Sheng Gao,Li-Xin Wang,Ying Liu,Guang-Feng Hou

doi:10.1107/s1600536810024773

Ying-Hui Yu, Jin-Sheng Gao + Show 3 more

Open Access

https://doi.org/10.1107/s1600536810024773

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Abstract

In the title compound, [Cu(NO3)2(C18H16N2O2)], the CuII ion is six-coordinated in a Jahn–Teller-distorted octahedral environment defined by two O and two N atoms from the ligand and two O atoms from two monodentate nitrate anions.

Highlights

In the title compound, [Cu(NO3)2(C18H16N2O2)], the CuII ion is six-coordinated in a Jahn–Teller-distorted octahedral environment defined by two O and two N atoms from the ligand and two O atoms from two monodentate nitrate anions
As a part of our continuing work for bipyridyl aromatic ligands, we report the crystal s tructure of the title compound here
Symmetry codes: (i) −x+1, −y+2, −z; (ii) −x, −y+2, −z; (iii) −x, −y+2, −z+1; (iv) −x, −y+1, −z+1

Summary

Structure Reports Online

Key indicators: single-crystal X-ray study; T = 291 K; mean (C–C) = 0.005 A; R factor = 0.046; wR factor = 0.111; data-to-parameter ratio = 15.4. In the title compound, [Cu(NO3)2(C18H16N2O2)], the CuII ion is six-coordinated in a Jahn–Teller-distorted octahedral environment defined by two O and two N atoms from the ligand and two O atoms from two monodentate nitrate anions. Related literature For the synthesis and general backround to flexible pyridylbased ligands, see: Liu et al (2010). See: Zhang et al (2010). Crystal data [Cu(NO3)2(C18H16N2O2)] Mr = 479.90 Triclinic, P1 a = 8.621 (5) Ab = 10.826 (6) Ac = 10.887 (6) A = 78.75 (2) = 77.590 (19)

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