Abstract
In the title compound, [Ru3(C6H12Cl3O3P)(C29H30P2)(CO)9], the bis(di-o-tolylphosphanyl)methane ligand bridges one Ru—Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru3 triangle. Each Ru atom bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings in the diphenylphosphanyl groups are 79.52 (10) and 69.88 (10)°. In the crystal, molecules are linked via C—H⋯O hydrogen bonds into chains along [100].
Highlights
Experimental a Crystal data11800 USM, Penang, Malaysia, and bX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia
Ru—Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru3 triangle
The dihedral angles between the two benzene rings in the diphenylphosphanyl groups are 79.52 (10) and 69.88 (10)
Summary
11800 USM, Penang, Malaysia, and bX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia. R factor = 0.016; wR factor = 0.042; data-to-parameter ratio = 18.9. In the title compound, [Ru3(C6H12Cl3O3P)(C29H30P2)(CO)9], the bis(di-o-tolylphosphanyl)methane ligand bridges one. Ru—Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru3 triangle. Each Ru atom bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings in the diphenylphosphanyl groups are 79.52 (10) and 69.88 (10). Molecules are linked via C—H O hydrogen bonds into chains along [100]
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