Abstract
The title compound, [Mo2(C15H15N2O2)3(C7H5O2)]·CH2Cl2, has a quadruply bonded Mo2 4+ unit equatorially coordinated by three N,N′-bis(4-μ-methoxyphenyl)formamidinate (DAniF) ligands and one benzoate anion. The Mo—Mo bond length of 2.0881 (8) Å is typical for quadruply bonded species. The phenyl ring and the connected dimetal chelating ring (Mo2O2C) are nearly co-planar, making a dihedral angle of 3.24 (13)°. The dichloromethane solvent molecule is disordered over four sets of sites with occupancies of 0.3:0.3:0.2:0.2.
Highlights
Crystal dataKey indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.006 Å; disorder in solvent or counterion; R factor = 0.036; wR factor = 0.107; data-toparameter ratio = 13.8
N,N0 -bis(4--methoxyphenyl)formamidinate (DAniF) ligands and one benzoate anion
The Mo—Mo bond length of 2.0881 (8) Å is typical for quadruply bonded species
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.006 Å; disorder in solvent or counterion; R factor = 0.036; wR factor = 0.107; data-toparameter ratio = 13.8. The title compound, [Mo2(C15H15N2O2)3(C7H5O2)]CH2Cl2, has a quadruply bonded Mo24+ unit equatorially coordinated by three. N,N0 -bis(4--methoxyphenyl)formamidinate (DAniF) ligands and one benzoate anion. The Mo—Mo bond length of 2.0881 (8) Å is typical for quadruply bonded species. The phenyl ring and the connected dimetal chelating ring (Mo2O2C) are nearly co-planar, making a dihedral angle of. The dichloromethane solvent molecule is disordered over four sets of sites with occupancies of 0.3:0.3:0.2:0.2
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