Abstract

The title dinuclear CoII complex, [Co2(C8H7O2)4(C12H8N2)2(H2O)], has C2 symmetry with the coordinated water O atom located on a twofold axis. Two CoII ions are bridged by two methyl­benzoate (MBZ) anions and one water mol­ecule. Each CoII ion displays a distorted octa­hedral coordination geometry. π–π Stacking occurs between roughly parallel MBZ and phenanthroline (phen) ligands and between parallel phen ligands.

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