Abstract
The asymmetric unit of the title compound, C38H34Cl2O2Te2·H2O, contains two independent TeIV cations, each coordinated by three phenyl ligands, two Cl− anions and one acetic acid molecule in a distorted octahedral C3Cl2O geometry; the longer Te⋯Cl distances ranging from 3.2007 (11) to 3.4407 (11) Å and the longer Te⋯O distances of 3.067 (3) and 3.113 (3) Å indicate the weak bridge coordination. The Cl− anion and acetic acid molecule bridge the two independent TeIV cations, forming the dimeric complex molecule, in which the Te⋯Te separation is 3.7314 (4) Å. In the crystal, the water molecules of crystallization link the TeIV complex molecules into chains running along the b-axis direction via O—H⋯O and O—H⋯Cl hydrogen bonds.
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