Crystal structure of 4,6-di-amino-2,2-dimethyl-3-[3-(2,4,5-tri-chloro-phen-oxy)prop-oxy]-2,3-di-hydro-1,3,5-triazin-1-ium chloride methanol monosolvate.

Pattarapol Khongsuk,Samran Prabpai,Palangpon Kongsaeree

doi:10.1107/s205698901501378x

Pattarapol Khongsuk, Samran Prabpai + Show 1 more

Open Access

https://doi.org/10.1107/s205698901501378x

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Abstract

In the title methanol-solvated salt, C14H19Cl3N5O2 +·Cl−·CH3OH, the triazine molecule is protonated at one of the triazine N atoms. In the crystal, the triazine cations are linked through a pair of N—H⋯N hydrogen bonds, with graph-set R 2 2(8), forming an inversion dimer. The protonated N atom and the 2- and 4-amino groups of the triazine cation interact with the chloride anion through N—H⋯Cl hydrogen bonds, leading to the formation of a tape structure running along the b-axis direction. A short Cl⋯Cl contact [3.2937 (9) Å] is observed in the tape. The methanol molecule is linked to the chloride anion and the triazine cation, respectively, by an O—H⋯Cl hydrogen bond and a C—H⋯O interaction.

Highlights

In the title methanol-solvated salt, C14H19Cl3N5O2+ClCH3OH, the triazine molecule is protonated at one of the triazine N atoms
The triazine cations are linked through a pair of N—H N hydrogen bonds, with graph-set
The protonated N atom and the 2- and 4-amino groups of the triazine cation interact with the chloride anion through N—H Cl hydrogen bonds, leading to the formation of a tape structure running along the b-axis direction

Summary

Introduction

In the title methanol-solvated salt, C14H19Cl3N5O2+ClCH3OH, the triazine molecule is protonated at one of the triazine N atoms. The triazine cations are linked through a pair of N—H N hydrogen bonds, with graph-set The protonated N atom and the 2- and 4-amino groups of the triazine cation interact with the chloride anion through N—H Cl hydrogen bonds, leading to the formation of a tape structure running along the b-axis direction.

Results

Conclusion