Abstract

Radical polymerization with reversible chain transfer by the addition-fragmentation mechanism of 5-vinyltetrazole in the presence of dibenzyltrithiocarbonate was carried out. The kinetics of the polymerization was studied by NMR spectroscopy: data on the conversion of the monomer and dibenzyltrithiocarbonate, and the rate of polymerization were obtained and analyzed. A comparison was made with the kinetics of the classical radical polymerization of 5-vinyltetrazole

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