Abstract

This review describes the method of Britt and Luecke (1973), which is applicable to the calculations of parame-ters relevant to the mixing properties of solid solutions. Based on the experimental results on ion-exchange reactions of (Fe, Mn, Mg)TiO3-(Fe, Mn, Mg)Cl2(aq) at 600°C and 98MPa (Kubo et al., 1992), this paper computes the Wilson parame-ters for the (Fe, Mn, Mg)TiO3 solid solution and the Gibbs energy changes of the individual binary exchange reactions.

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