Abstract

(Pb,Sr)TiO<TEX>$_3$</TEX>(PST) thin films have attracted great interest as new dielectric materials of capacitors for Gbit dynamic random access memories. In this study, inductively coupled CF<TEX>$_4$</TEX>/Ar plasma was used to etch PST thin films. The maximum etch rate of PST thin films was 740 <TEX>$\AA$</TEX>/min at a CF<TEX>$_4$</TEX>(20 %)/Ar(80 %) 9as mixing ratio, an RF power of 800 W, a DC bias voltage of -200 V, a total gas flow of 20 sccm, and a chamber pressure of 15 mTorr. To clarify the etching mechanism, the residue on the surface of the etched PST thin films was investigated by X-ray photoelectron spectroscopy. It was found that Pb was mainly removed by physically assisted chemical etching. Sputter etching was effective in the etching of Sr than the chemical reaction of F with Sr, while Ti can almost removed by chemical reaction.

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