Abstract
A fractal model of the structure of polymer macromolecules in solution is used to derive an analogue of Mark-Kuhn-Houwink-Sakurada empirical equation linking the intrinsic viscosity of the solution with the molecular mass of the polymer. It is shown that in addition to the molecular mass, the theoretically obtained equation – on the basis of the intrinsic viscosity – makes it possible to determine the size of Kuhn's rigid segment of the polymer and the fractal dimension of the polymer coils that characterize the structure of macromolecules in solution
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More From: Bulletin of the Saint Petersburg State Institute of Technology (Technical University)
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