추출 및 건조방법이 다시마 (Laminaria japonica) 알긴산의 물성에 미치는 영향

Abstract

In order to choose the manufacturing method for extracting alginates from sea tangle, Laminaria japonica, three methods were applied. In Method I, alginates were extracted with NaOH solution from sea tangle powder and extracted alginates were precipitated and converted to alginic acid by <TEX>$CaCl_2$</TEX> and HCI solution. Then alginic acid was converted to sodium alginates with <TEX>$Na_2CO_3$</TEX> solution. Sodium alginates were precipitated with methyl alcohol and were resolved with hot water and this step was repeated three times. Method II was same to Method I except final step including that sodium alginates were precipitated and washed with methyl alcohol three times. Method III included that sodium alginates were extracted with <TEX>$Na_2CO_3$</TEX> solution from sea tangle powder then sodium alginates were precipitated and washed with methyl alcohol three time. Extracting time increased with Increasing extracted alginates amounts but increasing rates were below <TEX>$0.4\%/h.$</TEX> Alginates amounts recovered by Method III showed above 2 times more to those by Method I and II. Extracting time increased with increasing ash amount of sodium alginates but increasing rates were below <TEX>$0.1\%/h.$</TEX> and that of sodium alginates extracted by Method III showed higher value <TEX>$(5\%)$</TEX> than those by Method I and II. In the sodium alginates prepared by Method III, the amount of ash in alginates dried by air was <TEX>$34.4\%,$</TEX> that by vacuum freeze drying was <TEX>$47.8\%.$</TEX> Extracting time increased with decreasing average molecular weight (MW) and degree of polymerization (DP) of sodium alginates, MW and DP of alginates prepared by Method III were higher than those by Method I and II In same extracting time. Extracting time increased with decreasing rate of apparent viscosity change (SAV) of alginates solution, and SAV of alginates prepared by Method III showed higher value than those by Method I and II in same extracting time. SAV of alginates dried by air was higher than that by vacuum freeze drying. Relating equation among SAV MW and DP were MW = 60.066 (SAV) -93.950, DP =309.760 (SAV) -485.084 and MW = 0.914 (DP)+0.213.