Abstract
The set of 4-aryl(hetaryl)pyrimidines, where aryl/hetaryl is a highly electron donating substituent was synthesized. Optical and electrochemical properties of the synthesized compounds were studied and the values of a forbidden band gap energy ( ) were determined. The narrowest bandgap was found to be inherent to 4-ferrocenylpyrimidine (1.8 eV) and the most long-wavelength emission maximum ‑ to para-substituted pyrimidine which structure embeds a thiophene moiety between N-hexylcarbazolyl fragment and the pyrimidine core (577 нм).
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Schedule a callMore From: Вестник Пермского университета. Серия «Химия» = Bulletin of Perm University. CHEMISTRY
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