電池・イオン導電性材料 固体酸化物燃料電池のカソード材料としてのＬｎ１−ｘＳｒｘＭｎＯ３（Ｌｎ＝Ｌａ，Ｐｒ，Ｎｄ，Ｓｍ ａｎｄ Ｇｄ）

Abstract

The perovskite type manganite systems, Ln1-xSrxMnO3 (Ln=La, Pr, Nd, Sm and Gd; 0.0≤x≤0.5) were studied as the electrode materials for solid oxide fuel cells (SOFC) from the view point of applications to the co-firing process of the electrolyte and electrode at higher temperature. The reactivity tests with yttria-stabilized zirconia (YSZ), no reaction product appeared between the Ln1-xSrxMnO3 perovskite and YSZ even at a high annealing temperature of 1400°C when the lanthanoid elements were Pr, Nd and Sm and the Sr content was around 30% (x=0.3). The adjustment of the thermal expansion rate of Ln1-xSrxMnO3 to YSZ, around x=0.1-0.2 in La1-xSrxMnO3, 0.3 in Pr1-xSrxMnO3 and Nd1-xSrxMnO3 and more than 0.4 in Sm1-xSrxMnO3 and Gd1-xSrxMnO3. The electrical conductivity reached to 200 S/cm at 1000°C for all Ln0.7Sr0.3MnO3 systems. The polarization measurements as an air electrode showed no significant dependence on the kind of lanthanoid elements. In the point of the electrode activity, high electrical conductivity, and low reactivity and good compatibility with YSZ, Pr0.7Sr0.3MnO3 and Nd0.7Sr0.3MnO3 are considered to be the most suitable electrode materials for the co-firing process.