The cohesive zone law represents the constitutive traction versus separation response along the crack-tip process zone of a material, which bridges the microscopic fracture process to the macroscopic failure behavior. Elucidating the exact functional form of the cohesive zone law is a challenging inverse problem since it can only be inferred indirectly from the far-field in experiments. Here, we construct the full functional form of the cohesive traction and separation relationship along the fracture process zone from far-field stresses and displacements using a physics-informed neural network (PINN), which is constrained to satisfy the Maxwell-Betti's reciprocal theorem with a reciprocity gap to account for the plastically deforming background material. Our numerical studies simulating crack growth under small-scale yielding, mode I loading, show that the PINN is robust in inversely extracting the cohesive traction and separation distributions across a wide range of simulated cohesive zone shapes, even for those with sharp transitions in the traction-separation relationships. Using the far-field elastic strain and residual elastic strain measurements associated with a fatigue crack for a ZK60 magnesium alloy specimen from synchrotron X-ray diffraction experiments, we reconstruct the cohesive traction-separation relationship and observe distinct regimes corresponding to transitions in the micromechanical damage mechanisms.