Zircon Saturation Temperatures Research Articles

Genesis of Rare Metal Granites in the Nubian Shield: Tectonic Control and Magmatic and Metasomatic Processes

The Igla Ahmr region in the Central Eastern Desert (CED) of Egypt comprises mainly syenogranites and alkali feldspar granites, with a few tonalite xenoliths. The mineral potential maps were presented in order to convert the concentrations of total rare earth elements (REEs) and associated elements such as Zr, Nb, Ga, Y, Sc, Ta, Mo, U, and Th into mappable exploration criteria based on the line density, five alteration indices, random forest (RF) machine learning, and the weighted sum model (WSM). According to petrography and geochemical analysis, random forest (RF) gives the best result and represents new locations for rare metal mineralization compared with the WSM. The studied tonalites resemble I-type granites and were crystallized from mantle-derived magmas that were contaminated by crustal materials via assimilation, while the alkali feldspar granites and syenogranites are peraluminous A-type granites. The tonalites are the old phase and are considered a transitional stage from I-type to A-type, whereas the A-type granites have evolved from the I-type ones. Their calculated zircon saturation temperature TZr ranges from 717 °C to 820 °C at pressure < 4 kbar and depth < 14 km in relatively oxidized conditions. The A-type granites have high SiO2 (71.46–77.22 wt.%), high total alkali (up to 9 wt.%), Zr (up to 482 ppm), FeOt/(FeOt + MgO) ratios > 0.86, A/CNK ratios > 1, Al2O3 + CaO < 15 wt.%, and high ΣREEs (230 ppm), but low CaO and MgO and negative Eu anomalies (Eu/Eu* = 0.24–0.43). These chemical features resemble those of post-collisional rare metal A-type granites in the Arabian-Nubian Shield (ANS). The parent magma of these A-type granites was possibly derived from the partial melting of the I-type tonalitic protolith during lithospheric delamination, followed by severe fractional crystallization in the upper crust in the post-collisional setting. Their rare metal-bearing minerals, including zircon, apatite, titanite, and rutile, are of magmatic origin, while allanite, xenotime, parisite, and betafite are hydrothermal in origin. The rare metal mineralization in the Igla Ahmr granites is possibly attributed to: (1) essential components of both parental peraluminous melts and magmatic-emanated fluids that have caused metasomatism, leading to rare metal enrichment in the Igla Ahmr granites during the interaction between rocks and fluids, and (2) structural control of rare metals by the major NW–SE structures (Najd trend) and conjugate N–S and NE–SW faults, which all are channels for hydrothermal fluids that in turn have led to hydrothermal alteration. This explains why rare metal mineralization in granites is affected by hydrothermal alteration, including silicification, phyllic alteration, sericitization, kaolinitization, and chloritization.

Two episodes of extension induced by slab rollback and root foundering in the Eastern Tianshan, southwestern Altaids: Insights from granites and intermediate dykes

The widespread Late Paleozoic-Early Mesozoic magmatism in the Eastern Tianshan provides critical insights into geodynamic evolution of the southern Altaids. In this study, we conduct an integrated study of field geology, petrology, U-Pb zircon geochronology and major-trace elemental and Sr–Nd–Hf isotopic geochemistry on the Late Carboniferous monzogranite and diorite dyke and the Late Triassic gabbroic diorite dyke in the central part of the Eastern Tianshan. Geochronological data indicate that the monzogranite, diorite dyke and gabbroic diorite dyke formed at ∼318 Ma, ∼317 Ma and ∼235 Ma, respectively. The Late Carboniferous monzogranite shows transitional characteristics between highly fractionated and A-type granites, with relatively high zircon saturation temperatures (800–836 °C). It was derived by partial melting of juvenile infracrustal rocks, followed by plagioclase-dominated fractional crystallization. The Late Carboniferous diorite dyke has high Al2O3 contents (mostly >17 wt%) and Ba/La ratios, indicating an origin from a hydrous lithospheric mantle source that had been metasomatized by slab-derived fluids. The Late Triassic gabbroic diorite dyke, with relatively high Mg# values (57–58) and Th contents (3.28–3.46 ppm), originated from a less hydrous lithospheric mantle source containing significant sediment-derived components. Our new results, combined with previous studies, reveal an end-Early Carboniferous to middle Late Carboniferous magmatic flare-up in the Dananhu arc. The magmatic flare-up occurred in a long E-W trending banded zone parallel to the strike of the arc and was accompanied by significant normal arc magmatism, which widely migrated to the south of the Dananhu arc in comparison to prior magmatism. These together with coeval extension-related volcanic, sedimentary, structural and metamorphic events in the Dananhu and adjacent areas were attributed to southward rollback of the subducted Kanguer oceanic slab. The long-time arc magmatism and regional crustal thickening before the Late Triassic led to the formation of an arclogite-bearing root beneath the Dananhu arc. The Late Triassic extension-related magmatism in the Dananhu arc, which was synchronous with or slightly younger than regional thickened crust-derived magmatism, was linked to the local root foundering of the long-lived Dananhu arc at the late stage of orogenesis. The episodic occurrence of geodynamic processes such as slab rollback, arc root foundering and ridge subduction/slab tearing, which were accompanied by massive input of juvenile materials into continental crust, contributed to multi-stage significant crustal growth in southern Altaids.

Eocene rhyolites in the Shanglaxiu-Xialaxiu area of north-eastern Qiangtang Block, Tibet: Partial melting of juvenile crust?

Many granitoids and their eruptive equivalents are substantially derived from the uppermost proportion of continental crust, and so their petrogenesis and source are significant in understanding the evolution and characteristics of continental crust. The Eocene felsic rocks in the Qiangtang block (central Tibet) commonly have enriched Nd isotope compositions and have been considered to be related to the recycling of ancient continental crustal material. In this paper we report new data on early Eocene felsic rocks with positive εNd(t) values in the northeastern Qiangtang block, which can be used to help understand Cenozoic evolution and characteristics of continental crust in the Qiangtang block. These rocks consist of rhyolites and occur in the Shanglaxiu and Xialaxiu areas in the north−eastern Qiangtang block. Zircon U−Pb dating yields ages of 47.8 ± 0.6 and 44.2 ± 0.7 Ma for the Shanglaxiu and Xialaxiu rhyolites, respectively, and so they represent the earliest record of Eocene magmatism in the Qiangtang block. The Shanglaxiu−Xialaxiu rhyolites have relatively low calculated zircon saturation temperatures (719–819 °C), along with high SiO2 (74.8–83.3 wt%) and K2O (5.1–7.8 wt%) contents, and low MgO (0.2–0.3 wt%), Cr and Ni contents. They are enriched in light rare earth elements (LREEs), Rb, K, Th, Zr, and Hf, and are depleted in Nb, Ta, Ti, Sr, and P, with moderately negative Eu anomalies. The Shanglaxiu rhyolites have positive whole−rock εNd(t) (0.3–0.4) and zircon εHf(t) (1.8–10.4), and variable zircon δ18O (6.3–7.3‰). The Xialaxiu rhyolites have slightly different whole−rock εNd(t) (−1.5 to −1.6), but similar zircon εHf(t) (2.2–7.7) and δ18O (6.7–7.2‰). We propose that the Shanglaxiu−Xialaxiu rhyolites were most probably generated by partial melting of the pre−existing juvenile crust with the addition of minor sedimentary material. This partial melting was possibly triggered by the south−dipping continental subduction of the Songpan−Ganzi block. The pre−existing juvenile crust was probably formed during the subduction of Paleo−Tethyan oceanic slab in Paleozoic−Early Mesozoic.

Early Devonian Post‐collisional Granitic Magmatism in the North Qilian Orogenic Belt, Western China: Insights into Lithospheric Delamination and Orogenic Collapse

AbstractPost‐collisional magmatism contains important clues for understanding the reworking and growth of continental crust, as well as lithospheric delamination and orogenic collapse. Early Devonian magmatism has been identified in the North Qilian Orogenic Belt (NQOB). This paper reports an integrated study of petrology, whole‐rock geochemistry, Sm‐Nd isotope and zircon U‐Pb dating, as well as Lu‐Hf isotopic data, for two Early Devonian intrusive plutons. The Yongchang and Chijin granites yield zircon U‐Pb ages of 394–407 Ma and 414 Ma, respectively. Both of them are characterized by weakly peraluminous to metaluminous without typical aluminium‐rich minerals, LREE‐enriched patterns with negative Eu anomalies and a negative correlation between P2O5 and SiO2 contents, consistent with geochemical features of I‐type granitoids. Zircons from the studied granites display negative to weak positive εHf(t) values (–5.7 to 2.1), which agree well with those of negative εNd(t) values (−6.4 to −2.9) for the whole‐rock samples, indicating that they were derived from the partial melting of Mesoproterozoic crust. Furthermore, low Sr/Y ratios (1.13–21.28) and high zircon saturation temperatures (745°C to 839°C, with the majority being >800°C) demonstrated a relatively shallow depth level below the garnet stability field and an additional heat source. Taken together, the Early Devonian granitic magmatism could have been produced by the partial melting of ancient crustal materials heated by mantle‐derived magmas at high‐temperature and low‐pressure conditions during post‐collisional extensional collapse. The data obtained in this study, when viewed in conjunction with previous studies, provides more information about the tectonic processes that followed the closure of the North Qilian Ocean. The tectonic transition from continental collision to post‐collisional delamination could be constrained to ∼430 Ma, which is provided by the sudden decrease of Sr/Y and La/Yb ratios and an increase in zircon εHf(t) values for granitoids. A two‐stage tectonic evolution model from continental collision to post‐collisional extensional collapse for the NQOB includes (a) continental collision and crustal thickening during ca. 455–430 Ma, characterized by granulite‐facies metamorphism and widespread low‐Mg adakitic magmatism; (b) post‐collisional delamination of thickened continental crust and extensional collapse of orogen during ca. 430–390 Ma, provided by coeval high‐Mg adakitic magmatism, A‐type granites and I‐type granitoids with low Sr‐Y ratios.

Petrogenesis and Tectonic Implications of the Oligocene Dalongtan Shoshonitic Syenite Porphyry in Central Yunnan, Southeastern Tibetan Plateau: Constraints from Geochronology, Geochemistry and Sr-Nd-Hf Isotopes

Shoshonitic rocks are widely distributed in post-collisional settings and provide key information on deep geodynamic mechanisms and magmatic evolution. In this paper, we present petrographic, zircon U-Pb age-related, trace elemental, Hf isotopic, bulk-rock elemental, and Sr-Nd isotopic data of the Dalongtan shoshonitic syenite porphyries (DSSPs) in central Yunnan, southeastern Tibet. The DSSPs formed at 33.2 ± 0.3 Ma in a post-collisional setting. They define linear trends on Harker diagrams, and they display similar trace element patterns and enriched bulk-rock Sr-Nd isotopes [(87Sr/86Sr)i = 0.70964–0.70968, εNd(t) = −12.9 to −12.7] and zircon Hf isotopes (εHf(t) = −15.7 to −13.1) to the coeval mantle-derived potassic mafic rocks. This suggests that the DSSPs were fractionated from the lithospheric mantle-derived mafic magmas. The DSSPs, along with the coeval felsic and mafic magmatic rocks (37.2–32.3 Ma), exhibit a planar distribution on the SE Tibet and predate the left-lateral shearing of the Ailaoshan–Red River shear zone (ARSZ) (32–22 Ma), suggesting that there are no genetic relationships between them. The DSSPs have geochemical characteristics similar to those of A-type granites, with high total alkalinity (10.39–11.17 wt.%), HFSE concentrations (Zr + Nb + Ce + Y = 890.2–1054.3 ppm), Ga/Al ratios (10,000 × Ga/Al = 2.95–3.46), whole-rock zircon saturation temperatures (906–947 °C), and oxygen fugacity (ΔFMQ = +3.30–+4.65), indicating that they are products of the high-temperature melting of the lithosphere as a result of asthenosphere upwelling in extensional settings. Based on our data and regional observations, it is proposed that the generation of the DSSPs may be linked to the convective thinning of the thickened lithospheric mantle following the India–Asia collision.

Whole-rock geochemical and zircon U-Pb-Hf isotopic compositions of the Yunlougang and Wucun granitic plutons in the Hetai area of South China: Implications for petrogenesis and geodynamic setting

In the Nanling tectono-magmatic belt of South China, the geodynamic settings and tectonic style of Indosinian and Yanshanian magmatism remain debatable. Hereby, an integrated study of zircon U-Pb ages and Lu-Hf isotopes as well as whole-rock elemental and Sr-Nd isotopic compositions was carried out on the Yunlougang (Late Permian) and the Wucun (Late Jurassic) granitic plutons in the Hetai area, located to southwest of the Nanling region. Zircon U-Pb dating yielded emplacement ages of 255 Ma for the Yunlougang biotite monzogranite, 240 Ma for the Yunlougang granodiorite as dyke crosscutting the former, and 155 Ma for the Wucun two-mica granite. The biotite monzogranite and the two-mica granite are strongly peraluminous S-type granites (A/CNK ratios of 1.06–1.21) with a relatively low zircon saturation temperature (631–741 °C). The high initial 87Sr/86Sr ratios (0.71733 to 0.73383) and low εNd(t) values (−14.6 to −8.69) suggest a crustal protolith. However, the Wucun biotite granite is highly fractionated I-type one (most samples are metaluminous with A/CNK < 1.1) with a relatively high zircon saturation temperature (762–770 °C). Additionally, they exhibit less radiogenic 87Sr/86Sri ratios (0.70724–0.70786) and higher εNd(t) values (−5.34 to −4.94) as well as zircon εHf(t) values of −5.67 to −2.44, suggesting an origin of a crustal source with extra input from mantle. Based on the tectonic history of South China, we infer that the Yunlougang granite occurred in a compressive setting and might be produced by partial melting of a thickened ancient crust during the collision between the South China and the Indochina blocks, while the Wucun complex granites generated in an extensional environment that was influenced by the paleo-Pacific tectonic regime. Combined with previous studies, a NE-oriented I-type granite belt probably existed along the juncture belt of the Yangtze and Cathaysia blocks, which was respond to the foundering rather than rollback of the paleo-Pacific plate that led to the rapid change of the temperature of granite precursor and the involvement of mantle components into the Hetai region.

Petrogenesis and geodynamic implications of the Late Devonian dioritic and granitic intrusive rocks in the Dananhu Belt, Eastern Tianshan Orogenic Belt

The Late Devonian magmatism of the Dananhu arc belt in the Central Asian Orogenic Belt provides a critical geological record. This study provides new comprehensive geochronological, geochemical, and Sr–Nd isotopic data of granodioritic and dioritic intrusions in the Dananhu belt. These findings contribute to unraveling the regional tectonic history and constraining the geodynamic processes involved. Zircon U–Pb dating indicates that the granodiorites and diorites were formed at 382.7 ± 3.8Ma and 363.1 ± 4.3Ma, respectively. The granodiorites show characteristics similar to I-type granites with high SiO2, low MgO and Mg# and aluminium saturation index (<1.1), negligible Eu anomalies, low (K2O + Na2O)/CaO ratios and zircon saturation temperatures (average = 696 °C). Granodiorites also show depleted isotope signatures (εNd(t) = +5.85 to +6.27 and low (87Sr/86Sr)i = 0.704082–0.704583) and juvenile TDM ages (741–793Ma), indicating their origin from a juvenile crust. The diorites are characterized by enrichments in large ion lithophile elements, U and Pb, but depleted in Nb and Ta displaying typical geochemical features of a subduction-related origin, together with high εNd(t) (+6.10 to +6.84) and low initial Sr isotopes (0.703745–0.704601), suggesting that they originated from a subduction fluid modified depleted mantle. The petrogenesis of both granodiorites and diorites in the Dananhu arc provides evidence that they formed through magmatic processes in a subduction tectonic setting. Considering the adakites associated with slab melting from previous studies in the Dananhu arc, it is plausible that the north-dipping subduction of the North Tianshan oceanic lithosphere have contributed to the Dananhu arc magmatism during the Late Devonian.

Comparison of Sn-related granitoids in subduction and collision settings by accessory mineral geochemistry: A case study in the Tengchong-Lianghe tin belt, SW China

Magmatic-hydrothermal Sn deposits can develop in both subduction and collision settings. However, a systematic comparison of the geochemical fingerprints and petrogenetic evolution of Sn-related granitoids from both settings is still lacking. The Tengchong-Lianghe tin belt hosts numerous Sn deposits but of different metallogenic ages, such as the Xiaolonghe and Lailishan Sn deposits, which provide an ideal study area for addressing this issue. Zircon U–Pb dating suggests that the Xiaolonghe and Lailishan Sn-related granitoids were emplaced at 74.2–75.5 and 50.0–51.1 Ma, respectively. Given the initial India-Asia collision commenced at ca. 65–60 Ma, these ages, consistent with available Sn metallogenic ages, suggest the formation of the Xiaolonghe and Lailishan Sn deposits in subduction and collisional settings, respectively. New zircon and apatite compositions, and apatite Sr isotopic data, combined with previously reported whole-rock geochemical results, all indicate that the Xiaolonghe and Lailishan Sn-related granitoids share similar magma sources, evolution processes, redox states, and volatile contents. The presence of hornblende, high apatite NdN/NdN* (mostly > 1), and whole-rock evolutionary trends, together indicate that they represent fractionated I-type granites. Distinctly elevated apatite 87Sr/86Sr ratios (0.70988–0.71430) suggest that they originated from an ancient lower crust. Subsequently, they underwent an extensive fractional crystallization dominated by feldspar, as revealed by whole-rock, apatite, and zircon elemental variation trends. The low zircon CeN/CeN* (mainly < 200) and ΔFMQ (–1.9 to 1.7), together with elevated apatite F content (2.30–3.69 wt%), reveal that they crystallized from reduced and F-rich magmas. The relatively high whole-rock zircon saturation temperatures (mainly > 800 ℃) and Ba/Pb ratios imply that they were produced at a higher temperature by biotite-dehydration melting, which requires additional heat from the mantle. The specific mechanism that triggers mantle upwelling (oceanic slab subduction or break-off) could be the most significant difference between Sn-related granitoids formed during subduction and collision processes.

Geochronology and geochemistry of granitoids from northern Alxa, northwest China: Petrogenesis and tectonic implications

AbstractMultiple branch oceans existed in the Paleo‐Asian Ocean (PAO), but their closure times are in dispute and unclear, which constrains our understanding of the final closure time of the PAO and the tectonic evolution of the Central Asian Orogenic Belt (CAOB). This study focuses on the Permian plutons of the northern Alxa, which is located in the middle segment of the southern CAOB that recorded the final subduction history of the PAO. We performed the 1:50000 mapping, whole‐rock geochemistry, geochronology, and Sr‐Nd‐Hf isotopic analysis and compiled the Sr‐Nd‐Hf isotopic compositions and whole‐rock geochemical data of igneous rocks from the northern Alxa. LA‐ICP‐MS zircon U–Pb dating reveals the study plutons emplaced in the Early Permian (285–296 Ma). Whole‐rock geochemical data show the intrusion belongs to medium‐K calc‐alkaline peraluminous highly fractionated I‐type granite, enriched in Rb, K, Th, Pb, and depleted in Nb, Ta, Ti, Sr, and P elements, which suggest a subduction arc‐related setting and metaluminous to weak peraluminous parental magma. The weak negative εNd(t) (from −2.3 to −1.2), relatively high ISr (0.704772–0.708037) and depleted mantle model ages TDM (1.14–1.49 Ga), combining with weak negative to slightly positive εHf(t) (from −2.0 to +4.1) and crustal model ages TDMC (1.18–1.43 Ga), indicate that the parental magma might originate from remelting of the Mesoproterozoic lower crust and mixing with mantle‐derived materials. The field occurrence, deformation, and geochemical features, integrating with the compiled data and regional geology, show that the igneous rocks formed before or after the late Early Permian show different features in terms of deformation, zircon saturation temperatures, crustal thickness, potassium contents, and εHf(t) values. This might relate to the closure of the Yagan branch ocean of the PAO in northern Alxa.

Zircon U[sbnd]Pb and Hf isotope insights into the Mesoproterozoic breakup of supercontinent Columbia from the Sausar Belt, Central Indian Tectonic Zone

Credible records of rifting and associated sedimentation and granitoid magmatism coinciding with the Columbia breakup event are not common in the Precambrian Indian continent. We report a 1322 ± 3 Ma concordia age for magmatic zircons from the granitoid rocks of the Sausar mobile belt, Central Indian Tectonic Zone (CITZ). The rocks exhibit geochemical characteristics of A-type granitoid rocks and were generated by the dehydration melting of shallow crust in an extensional tectonic setting. The predominantly negative εHf(t) values and partial melting modelling imply their origin by the reworking of pre-existing granitoid crust. TDM2 (Hf) model ages for these rocks range from 2856 Ma to 1885 Ma suggesting a prolonged period of crustal evolution and reworking of Archean to Paleoproterozoic basement rocks. The temperature for magma generation, determined from the calculated zircon saturation temperature of 874.2 °C is suggestive of melting of a thinned crust that was heated by the upwelling asthenosphere in an extensional tectonic setting. The obtained ages provide evidence for the existence of an extensional event during mid-Mesoproterozoic coinciding with the Columbia breakup event. The extension could also be argued as a local event related to far-field stresses generated due to the ca. 1.6 to 1.5 Ga subduction-collision event at the plate margin farther to the north of the studied region of the CITZ. The recrystallized margins of zircon grains yield 207Pb/206Pb ages between 0.95 Ga and 1.0 Ga implying their alteration during a metamorphic event that can be identified with the final amalgamation and stabilization of the northern and southern Indian blocks along the CITZ, coinciding with the Rodinia assembly, during which the regional structural fabric developed.

Meso-Neoproterozoic tectonic-thermal events in the Qaidam Block, NW China and their geological significance: Constraints from drill cores geochronology and geochemistry studies

As a micro-continent lying at the junction of the North China, Yangtze, and Tarim Cratons in northwest China, the composition and tectonic-thermal history of the Qaidam Block not only are crucial for determining its tectonic attribute and relationships with surrounding cratons, but also can provide key constraints on convergence, fragmentation, and paleogeographic reconstruction of Columbia and Rodinia. In this study, systematic petrology, geochemistry, and zircon U–Pb–Hf isotope analyses were conducted on newly discovered Meso-Neoproterozoic granitic rocks from drill cores in the Qaidam basin and three stages granitic magmatism at ca. 1420 Ma, ca. 900 Ma and 780–750 Ma are yielded. The ca. 1420 Ma granitic rocks exhibit characteristics of highly fractionated I-type granites, with high Yb but low Sr contents, low Sr/Y and La/Yb ratios, high zircon saturation temperatures (774–831 ℃), and positive εHf(t) values (–0.04 to +11.35) with TDM2 values of 2178–1468 Ma, suggesting that they were mainly derived from the ancient crust with mantle magma input under an extensional setting. The ca. 900 Ma granitic rocks have high A/CNK values (1.01–1.21) and variable zircon εHf(t) values (–1.93 to + 6.58) with TDM2 ages between 1402 and 1910 Ma, indicating they are S-type granites formed by partial melting of sedimentary rocks in thickened crust. The ca. 780–750 Ma granites have high Zr + Nb + Ce + Y contents, 10000* Ga/Al ratios, and crystallization temperatures (mean = 808 ℃), belonging to the A1-type granite formed in a continental rift setting.Combined with the previous researches, the Meso-Neoproterozoic tectonic-thermal events in the Qaidam Block can be divided into three stages, 1.8–1.1 Ga, 1.0–0.9 Ga and 850–750 Ma, corresponding to the fragmentation of Columbia, and the assembly and breakup of Rodinia, respectively. Comparing the Qaidam Block with the surrounding blocks and the major cratons in Columbia and Rodinia, it is considered that the Qaidam Block was splited from the Tarim Craton and they may have occupied an interior position in Columbia but a peripheral position in Rodinia, connecting to the India and East Antarctica.

Geochronology and petrochemistry of Karabiga pluton in western Sakarya Zone (NW Turkey): Implications from new zircon U-Pb and biotite Ar/Ar ages, Sr-Nd isotope data and bulk-rock geochemistry

The closure of the Neo-Tethys Ocean and the following continental collision produced extensive Eocene-aged granitic plutons in the northern margin of Gondwana. This paper deals with the geochronology and petrogenesis of the Karabiga pluton in western Sakarya Zone. The pluton comprises K-feldspar, plagioclase, hornblende, biotite, quartz and accessory minerals (e.g., titanite, zircon, apatite, opaques), and secondary minerals such as chlorite, sericite, epidote, carbonate and clay minerals. Laser ablation inductively coupled plasma mass spectrometer zircon U-Pb dating yielded perfect ages of 48.27 ± 0.21 and 47.06 ± 0.32 Ma, indicating that the pluton were emplaced in the Early Eocene. Our results indicate that Ti-in-zircon temperature (ca. 900 °C), which is consistent with zircons grew in the continental crust, are higher than zircon saturation temperatures (740–884 °C). 40Ar/39Ar dating of biotites of the pluton yielded cooling ages between 47.34 ± 0.43 Ma and 46.30 ± 0.52 Ma. These dates are interpreted as the cooling age of the Karabiga pluton. The pluton is characterized by high SiO2 (72.40–76.48 wt%), K2O (5.12–6.44 wt%) and Na2O (3.26–5.55 wt%) contents and exhibit enriched LREEs, K, Rb, Th, U, and Pb, and depleted Nb, Ta, P, and Ti contents. It belongs to shoshonite series, and displays peraluminous, I-type character. 87Sr/86S(i) ratios of the pluton vary between 0.703296 and 0.706654, while those of 143Nd/144Nd(i) lie between 0.512596 and 0.512629. In conclusion, Karabiga pluton could be originated from dehydration-melting of metagreywacke and metapelites in middle-upper crust due to slab breakoff/delamination and major, trace element contents, decreasing Al2O3, Fe2O3, MgO and TiO2 with increasing SiO2 as well as initial Sr-Nd homogenity show that fractional crystallization played a role in the evolution of the pluton.

U-Pb Geochronology, Geochemistry and Geological Significance of the Yongfeng Composite Granitic Pluton in Southern Jiangxi Province

The Yongfeng composite granitic pluton, located in the southern section of the Nanling area, is composed of the Yongfeng and Longshi biotite monzonitic granites. In order to reveal the genesis of this composite granitic pluton and its relationship with mineralization, this study conducted zircon U-Pb dating, whole-rock major and trace element analysis, and biotite electron probe analysis. The results show that the Yongfeng composite granitic pluton is rich in silicon and alkali, weakly peraluminous, and poor in calcium and iron. It shows the enrichment of light rare earth elements and a significant fractionation of light and heavy rare earth elements. It also shows the enrichment of large ion lithophile elements and depletion of Ba, K, P, Eu, and Ti relative to the primitive mantle. The contents of TFe2O3, MgO, CaO, TiO2, and P2O5 are low and decrease with increasing SiO2 content. The Yongfeng composite granitic pluton does not contain alkaline dark minerals. Its average zircon saturation temperature is 776 °C, average TFe2O3/MgO is 4.81, and average Zr + Nb + Ce + Y is 280.6 ppm, which correspond to a highly fractionated I-type granite. The Yongfeng and Longshi granites were respectively formed at 152.0 ± 1.0 Ma–151.3 ± 1.1 Ma and 148.9 ± 1.2 Ma. They were formed in the extensional tectonic setting during the post-orogenic stage, under the control of the breakup or retreat of the backplate after the subduction of the Pacific Plate into the Nanling hinterland. The magmatic system of the Yongfeng composite granitic pluton is characterized by high fractionation, high content of F, high temperature, and low oxygen fugacity, which is conducive to mineralization of Sn, Mo, and fluorite.

Late Cryogenian Circum-Rodinia Syn-Subduction Extension: Insights from Highly Fractionated S-Type and A-Type Granitoids in the Northern Tarim Craton

Late Cryogenian–Ediacaran magmatism represents the latest Precambrian tectonothermal event in the Tarim Craton. However, its geodynamic setting and geological significance are controversial. Here, we report the geochronology, whole-rock geochemistry, and Sr-Nd-Hf isotopic compositions of newly identified late Cryogenian A-type and highly fractionated S-type granites from two locations in the northern Tarim Craton. LA-ICP-MS zircon U-Pb analyses yield ages of 642 ± 7 Ma for a syenogranite and 643 ± 4.5 Ma for a mylonitized granite. The syenogranite is weakly peraluminous and shows an A-type granite affinity, as indicated by its high K2O + Na2O contents (8.35–8.64 wt.%), high field strength elements (Zr + Nb + Ce + Y = 435.8 − 463.4 × 10−6), Ga/Al ratios (2.79−2.83), and zircon saturation temperatures (829–844 °C). In contrast, the mylonitized granite contains Al-oversaturated minerals (e.g., garnet) and has high a differentiation index (DI = of 98.9–99.4), with lower zircon saturation temperatures (786–792 °C); the samples display high SiO2 contents (72.99–74.00 wt.%) and A/CNK values (1.16–1.17) and low Nb/Ta and Zr/Hf ratios and are enriched in Rb and depleted in Ba, Sr, which all point to a highly fractionated S-type granite affinity. The granites are characterized by elevated large-ion lithosphere elements (LILEs) and flat high-field-strength elements (HFSEs) patterns, with deep Nb and Ta troughs and pronounced negative Eu anomalies (Eu/Eu* = 0.17–0.38). They show apparently negative εNd(t) values (−10.1 to −9.8 and −6.8 to −7.9, respectively) and εHf(t) values (−9.66 to −1.77 and −33.5 to −1.3, respectively) with Paleoproterozoic crustal model ages, indicating that they were mainly generated by the partial melting of mature crustal materials with a minor contribution from a mantle-derived magmatic source. By integrating with previously published geological, sedimentological, and structural data, we suggest that the granites formed due to a high-temperature gradient in a syn-subduction extensional setting that was probably induced by northward slab rollback of the Paleo-Asian Oceanic lithosphere. Our new data highlight an upper-plate extension in the northern Tarim Craton that constitutes the northern periphery of the Rodinia supercontinent. The linear distribution of late Cryogenian magmatic rocks provides critical evidence for the orogen strike extension of the terminal suture between the Tarim Craton and southwestern Altaids.

Origin of Silurian granite in the Baiganhu field, Eastern Kulun Terrane, NW China: Implications for the tectonic setting of Sn-W mineralization

The Baiganhu area in the Eastern Kunlun Terrane on the northern margin of the Tibetan Plateau contains world-class Sn-W deposits in close association with monzogranite. However, the origin of granite and the tectonic setting for the Sn-W mineralization have not been well constrained. Here we present the petrological and geochemical data of the granite (431 Ma) associated with the Sn-W mineralization to evaluate the geological-tectonic setting for the mineralization. The monzogranite has high SiO2 contents, ranging from 65.8 to 73.5 wt%, and shows a geochemical affinity with A2-type granites. Relatively high zircon saturation temperatures, ranging between 750 °C and 921 °C, suggest that the parental magmas were hot. The whole-rock εNd (t = 431 Ma) values range from –2.7 to –3.1 with TDM ages between 1810 and 1040 Ma, and zircon εHf (t = 431 Ma) values range from + 0.7 to + 4.1 with TDM ages between 1040 and 900 Ma. The data suggest that the magmas had significant contributions of old rocks. The granitic rocks intruded into quartz-muscovite schist of the Proterozoic Xiaomiao Complex, which underlies the vast area. Zircon grains in the schist are magmatic in origin based on sharp oscillatory zoning and high Th/U ratios (>0.2). The 207Pb-206Pb zircon ages (n = 25) of the schist range from 1898 ± 2 to 1700 ± 6 Ma, suggesting that the zircon grains originate from a Paleoproterozoic magmatic belt. Such ancient rocks, either as lower crustal component or subcontinental lithospheric mantle, contributed ∼ 30 % to the parental magmas. We conclude that post-collisional extension within the Eastern Kunlun Terrane was accompanied by upwelling and adiabatic melting of the asthenospheric mantle which induced partial melting of subcontinental lithospheric mantle and lower crustal rocks and formed granitic magmas. Aqueous fluids separated from the granitic magma which preferentially incorporate W and Sn contributed to the mineralization in and around the granites.

Petrogenesis of the Eocene Highly Fractionated Granite Porphyry with REE Tetrad Effect: An Example from Western Yunnan, Southeastern Tibetan Plateau

Highly fractionated granites are widely distributed in the crust and provide unique windows into magmatic evolution. This study reports petrography, zircon U–Pb ages, trace elemental, and Hf isotopic, as well as whole-rock elemental and Nd isotopic data of highly fractionated granite porphyries from the Shiguanshan area in western Yunnan, southeastern Tibet. The granite porphyries were formed at 34.0 ± 0.3 Ma in a post-collisional setting. They are strongly peraluminous (A/CNK = 1.95–2.80), have high SiO2 content (SiO2 = 78.16–79.13 wt.%) and zircon saturation temperatures (803–829 °C, average 819 °C), and low MgO, with pronounced enrichment in Pb, U, Th, and Rb, and depletion in Ti, Eu, P, Sr, and Ba, and belong to highly fractionated A-type granites. These rocks define linear trends on Harker diagrams and display similar enriched whole-rock Nd isotopic (εNd(t) = −12.8 to −12.3) and zircon Hf isotopic (εHf(t) = −10.4 to −8.8) compositions compared to the published data of coeval mantle-derived syenite porphyries, which can be attributed to fractional crystallization processes. A quantitative model suggests that the Shiguanshan granite porphyries likely formed through the fractionation process of a mineral assemblage consisting of plagioclase, K-feldspar, biotite, and amphibole (in a ratio of 40:30:25:5), with fractionation degrees of 50%–55%. The magmatic textures and zircons, decoupling between the REE tetrad effect and fractionation of twin-elements, along with the modeling result of Rayleigh fractionation, suggest that the REE tetrad effect in the Shiguanshan granite porphyries may be caused by fractionation of accessory minerals. Our data, along with regional observations, propose that the generation of these granite porphyries is possibly related to lithospheric removal following the Indo–Asia collision.

Geochemical Composition Variations and Tectonic Implications of the Baoligaomiao Formation Volcanic Rocks from the Uliastai Continental Margin, Southeast Central Asian Orogenic Belt

Abstract The Permo-Carboniferous tectonic evolution in the Uliastai continental margin (UCM), north of the southeast central Asian Orogenic Belt, remains controversial. This work examined the geochemical composition of the felsic volcanic rocks from the lower and upper part of the Baoligaomiao Formation in the UCM. Zircon U-Pb ages reveal that the Baoligaomiao Formation has a long-lived eruption duration, from ca. 285 to 328 Ma. The lower part (ca. 328–310 Ma) of the Baoligaomiao Formation is dominated by clastic and pyroclastic rocks with subordinate intermediate-felsic volcanic rocks, whereas the upper part (ca. 307–285 Ma) mainly consists of felsic volcanic rocks and pyroclastic rocks. Calculations reveal that the felsic volcanic rocks from the lower part have low zircon saturation temperatures (TZr = 747℃–795℃), whereas those from the upper part exhibit high TZr (ca. 793℃–930℃). Zircons from the lower part exhibit high εHf(t) values and 176Lu/177Hf ratios, in contrast to the low εHf(t) values and 176Lu/177Hf ratios of zircons from the upper part. Those petrogeological and geochemical shifts might support the tectonic switch model in the UCM at the end of the Carboniferous, providing new constraints on the Late Carboniferous closure of the Hegenshan Ocean.

Triassic felsic magmatism in SE Peninsular Malaysia: Petrogenesis and geodynamic implications for the Eastern Paleotethyan tectonic transition

Middle–Late Triassic volcanism and contemporary granitoids in East Malaya provide significant insights into the magmatic evolution and geodynamic processes of the Paleotethyan Ocean in SE Asia. This paper presents new zircon ages and whole-rock geochemical data including Sr-Nd-Pb-Hf isotopic analyses for newly identified felsic volcanic rocks and granites in SE Peninsular Malaysia. Zircon geochronological data constrain their formation time at 238–235 Ma. All samples have relatively high SiO2 contents with enrichment in light rare earth elements but have negative anomalies at Nb, Ta, Ti, and Eu on spidergrams. Calculated zircon saturation temperatures are between 840 °C and 957 °C. Samples have (87Sr/86Sr)i ratios between 0.70501 and 0.71014 and εNd (t) values ranging from −6.6 to −5.9, with (206Pb/204Pb)i = 18.45–18.77, (207Pb/204Pb)i = 15.68–15.71, and (208Pb/204Pb)i = 38.88–38.97. The zircon in-situ εHf (t) values and TDM2 ages range from −5.6 to +4.5 and 1.62 Ga to 0.98 Ga, respectively. The primary melting source which produced these felsic volcanic rocks and granites was Proterozoic crustal rocks with a juvenile middle-lower crustal component. Triassic volcanism in SE Peninsular Malaysia northerly correlates with synchronous volcanic rocks in the Lancangjiang and Chiang Khong-Lampang-Tak volcanic zones. Our data, along with regional observations, indicate that these volcanic rocks and granites formed in a localized extensional setting in response to the Paleotethyan slab breakoff. While the initial collision of Sibumasu with East Malaya may have occurred at ∼237 Ma.

Middle Devonian Evandale porphyry Cu-Mo (Au) deposit, southwestern New Brunswick, Canada: Analysis of petrogenesis to potential as a source for distal intrusion-related epithermal gold mineralization

The 391.2 ± 3.2 Ma (U-Pb on zircon) Evandale Granodiorite of southwestern New Brunswick is quite a unique intrusive rock in the southern part of the northeastern Appalachians. This research examines the relationship between the porphyry Cu-Mo-(Au) and epithermal systems with Evandale Granodiorite and environs. This Middle Devonian multi-phase I-type granite intrudes along the northern boundary of the deformed Silurian sedimentary and mafic volcanic rocks of the Mascarene Basin. This granitoid is identified as an oxidized I-type system with adakitic geochemical signatures and associated porphyry Cu-Mo-(Au) mineralization, possibly linked to slab failure sourced from decompression melting of the lower crust caused by post-collisional uplift, similar to the Magaguadavic Granite to the southwest. The Evandale adakitic intrusion is divided into two phases that consist of (1) a calc-alkalic coarser phase ranging from medium- to coarse-grained, seriate to porphyritic granodiorite to monzogranite with metaluminous to peraluminous features, and (2) the later stage alkali-calcic fine-grained (to aplitic) locally porphyritic phase ranging from a monzogranite to syeno-granite with peraluminous characteristics. The primary mineralogy of the intrusive rocks consists of K-feldspar + albite + plagioclase + quartz + biotite + hornblende + apatite ± muscovite ± zircon, along with several alteration phases, such as biotite, chlorite, sericite, and calcite. Geochemical analyses (using INAA, ICP-MS, and XRF) indicate that both phases of the Evandale granodiorite show a high concentration of Cu (108 ppm) and Au (33 ppb) associated with the presence of pyrite, chalcopyrite, and arsenopyrite in the fine-grained dyke samples. Up to 6 ppm Mo was contained within the granitic phase, whereas lesser amounts of Mo were confined to the fine grained to aplite phases. Microprobe analyses of primary biotite as both phenocrysts and groundmass shows 0.55 avg. wt.% Cl and 0.21 avg. wt.% F, which are relatively concentrated compared to other high-grade porphyry deposits. Hydrothermally altered rocks, veins, and sulfides associated with the porphyritic suite result from buoyant magmatic-hydrothermal fluids from a deeper intrusion exsolving fluids (quenched porphyry related), depressurizing, and reacting with the host coarser grained granodiorite and even some of the dykes locally. Based on the geothermometry and geobarometry of amphibole (actinolite-magnesiohornblende), the crystallization temperature and pressure of the Evandale coarse-grained granite and aplite are 674–755 °C, 0.2–0.7 kbar (20–70 MPa) and 838 °C, 0.42–1.4 kbar (42–140 MPa), respectively. This is consistent with biotite formation at temperatures ranging from 670° to 760 °C, based on Ti-in-biotite thermometry. Also, zircon saturation temperatures of the earlier coarse-grained porphyritic granites and later fine-grained porphyry to aplitic dykes are 736 °C and 787 °C, respectively. Spatially and temporally associated gold deposits beside Evandale and within this region of southwestern New Brunswick suggests that these oxidized I-type intrusions are a potential source for distal, low sulfidation epithermal gold deposits in the region.

The geochemical characteristics of Cretaceous volcanics in southern Hainan Island and implications for tectonic evolution in the South China Sea

The southeastern Eurasian plate, where the South China Sea (SCS) is located, lies in a complex tectonic setting between the Pacific and Tethys tectonic belts. It is widely accepted that the tectonics of the SCS area were influenced by subduction in the late Mesozoic, but there is still controversy over whether it was paleo-Pacific subduction or Tethyan subduction. Volcanic activity in the south of Hainan Island was intense during the Cretaceous, and geochemical analysis of the collected basaltic andesite, andesite and rhyolite samples in this study indicate those intermediate-acid series igneous rocks are high-K calc-alkaline or calc-alkaline. Some andesites have high MgO contents and Mg# values (2.04–5.34 wt% and 36.83–55.29; Mg# = 100× Mg2+/(Mg2+ + TFe2+). Light rare earth elements (LREEs) and large ion lithophile elements (LILEs) are enriched in all the samples, but high field strength elements (HFSEs) are depleted. The negative Eu anomalies are more obvious in the rhyolites than andesites. The geochemical characteristics of the volcanic arc igneous rocks show that the mid-Cretaceous tectonic setting of Hainan Island can be classified as an Andean active continental margin. During the mid-Cretaceous, intermediate volcanism occurred in Hainan Island and its adjacent areas. The zircon-saturation temperatures of the acid volcanic rocks in study area exhibit relatively low values (ranging from 746°C–790°C). Unlike igneous rocks forming in the coastal area east of the South China Block at the same time, no A-type granitoids with alkaline dark minerals appear in Hainan Island. During the late Mesozoic, the western SCS, where Hainan Island was located, may not have been affected by the subduction of the paleo-Pacific Plate, but rather Neotethyan subduction which dominated the Cretaceous magmatic and tectonic activities along the western margin of the SCS. This finding helps to understand the late Mesozoic tectonic evolution of the southeastern edge of the Eurasian plate.