Zircon Oxygen Research Articles

Geochemical and zircon 18O–Hf–U/Pb isotopic study of volcanic rocks from Lutao Island in the northern Luzon magmatic arc

AbstractLutao is an islet off the eastern coast of the main island of Taiwan and is composed of pyroclastic agglomerates, volcanic breccias, lava flows, and dykes. There have been no reports of SIMS zircon oxygen isotopic data from Lutao Island so far, which has significantly hampered further understanding of its magmatic processes, such as crystallization, evolution, and generation of magma. In this study, we use zircon U–Pb dating, Lu–Hf and O isotopic analysis to constrain the age, origin, and magmatic processes of the volcanic rocks from Lutao Island. Integration of our new U–Pb and Hf–O isotope data with available published data allows us to better assess the timing and magmatic processes of Lutao Island in the context of the northern Luzon arc system. This work is the first report of SIMS zircon oxygen isotopic data of volcanic rocks from Lutao island. This study shows that the volcanic rocks from Lutao Island were generated by mantle-derived magma associated with high-T° hydrothermal alteration by seawater-derived fluids.

Transcrustal magmatic systems in NE China: Insights from Early Cretaceous metaluminous–peraluminous–peralkaline rock associations in the southern Great Xing’an Range

The generation and evolution of crustal-scale magmatic systems are important in revealing the continental crust differentiation. In the Bayangeer-Aliwula area of Inner Mongolia, metaluminous–peraluminous–peralkaline rock assemblages provide a rare opportunity to evaluate Early Cretaceous magmatic systems. This study presents new geochemical data, including whole-rock and zircon geochemistry, zircon U–Pb dating, and Hf–O isotopic analysis of rocks formed between 132 and 121 Ma. The metaluminous rocks exhibit low SiO2 (55.35–65.65 wt%), low Rb/Sr (0.08–0.24) and (La/Yb)N (4.88–7.58) ratios, and positive εHf(t) values (+4.9 to +8.7). These features, along with enrichment in large-ion lithophile elements and depletion in Nb and Ta, suggest formation via partial melting of fluid-metasomatised lithospheric mantle. By contrast, peraluminous rocks have high SiO2 (69.37–80.58 wt%), a high differentiation index (DI = 88–95), and Fe-index (0.84–0.95), resembling highly fractionated I-type granites. They show high Rb/Sr (0.77–3.35) and (La/Yb)N (5.79–22.75) ratios, and positive εHf(t) values (+6.7 to +10.8), combined with the modelling results, indicating origin from partial melting of K-rich mafic lower crust followed by magma fractionation. Peralkaline rocks display typical ferroan A-type granite characteristics (Zr + Nb + Ce + Y = 906–4292 ppm; Fe-index = 0.96–0.99), with high SiO2 (74.02–77.50 wt%), high Rb/Sr (6.17–121.38), and (La/Yb)N ratios (2.19–17.72), and positive εHf(t) values (+3.1 to +9.6). Zircon geochemistry characteristics suggest that peralkaline and peraluminous felsic melts are different batches extracted from the same magma reservoir. Further analysis, including hyperbola diagrams and zircon oxygen isotope compositions, suggests peralkaline magma formation through the mixing of altered oceanic crust fluids and peraluminous melts after melt extraction. During Early Cretaceous, the transcrustal magmatic system provides a reasonable explanation for the petrogenesis of various contemporaneous rocks in the study area in southern Great Xing’an Range.

A rapid transition from subduction to Barrovian metamorphism: geochronology of mafic–ultramafic relicts of oceanic crust in the Central Alps, Switzerland

Relicts of subducted oceanic lithosphere provide key information for the tectonic reconstructions of convergent margins. In the Central Alps, such relicts occur as isolated mafic–ultramafic lenses within the migmatites of the southern Adula nappe and Cima-Lunga unit. Analysis of the major-, minor-, and accessory minerals of these ophiolitic relicts, combined with zircon and rutile U–Pb ages and zircon oxygen isotopes, allows the reconstruction of different stages of their complex evolution. The mafic–ultramafic suite in Valle di Moleno consists of chlorite-harzburgites associated with metarodingites and retrogressed eclogites. Relic omphacite and kyanite in retrogressed eclogites provide evidence for subduction-related metamorphism. Increasing XPrp in the garnet mantle towards the rim documents heating during high-pressure metamorphism up to 800–850 °C. Polyphase inclusions and chemical zoning in garnet suggest fluid-assisted melting during high-pressure metamorphism dated at 31.0 ± 0.9 Ma. In Val Cama, chlorite-harzburgites, metarodingites and calcsilicate-metasediments occur. Detrital zircon ages in the metasediment suggest a Mesozoic deposition. The metarodingite-metaperidotite-metasediment association and the low δ18O signatures of zircon (δ18O 3.0–3.7‰), inherited from seafloor metasomatism of the protoliths, show that the rocks are derived from former altered oceanic crust. Amphibolite facies metamorphism related to the Central Alps Barrovian evolution in Val Cama occurred at 28.8 ± 1.5 Ma. The combined data from Moleno and Cama indicate a rapid transition (~ 2 Ma) from subduction to collisional metamorphism with corresponding exhumation rates of 3–6 cm/year. Fast exhumation tectonics may have been favored by slab break-off or slab extraction. U–Pb dating of rutile from both localities yields ages of ~ 20 Ma, suggesting that these rocks remained at amphibolite-facies conditions for about 10 Ma and underwent a second fast exhumation of 3 cm/year associated with vertical movements along the Insubric line.

Devonian plutons in the eastern Meguma terrane, Nova Scotia, Canada: zircon U–Pb, Lu–Hf, and O isotopic compositions, age, and petrogenetic implications

Abundant granitic plutons intruded the eastern Meguma terrane of Nova Scotia in the middle- to late Devonian. Less voluminous diorite–tonalite and gabbro intrusions are associated with the granitic plutons along the northern margin of the terrane adjacent to the Cobequid–Chedabucto fault zone. All plutons contain metasedimentary xenoliths, and the mafic plutons show magma mingling textures with their adjacent granitic plutons. New U–Pb zircon data from autocrystic zircon in 13 samples indicate coeval emplacement of mafic and granitic plutons between ca. 382 and 368 Ma. However, the zircon grains contain numerous inherited domains that range in age from Palaeoproterozoic to Devonian. These inherited ages correspond to detrital zircon U–Pb dates from the Cambrian to Ordovician metasedimentary host rocks. Zircon oxygen isotopic data (δ18O) are between +7.4 ± 0.2‰ and +9.3 ± 0.3‰ indicating significant involvement of the crust as the magma source or contaminant. If the high δ18Ozrn values are a result of contamination, the contaminant was likely the metasedimentary rocks of the Meguma terrane. Hafnium isotopic data from autocrystic zircon have εHf( t) between −6.0 ± 1.5 and +2.1 ± 2.5. The new zircon U–Pb, O, and Hf isotopic data from plutons in the eastern Meguma terrane are indistinguishable from published data from the South Mountain Batholith. The data suggest that Devonian magmatism in the Meguma terrane post-dated the main orogenic event that caused folding and regional metamorphism and involved the same magma source and/or contaminants throughout the terrane.

Multi-scale, open-system magmatic and sub-solidus processes contribute to the chemical and isotopic characteristics of the Jurassic Guadalupe Igneous Complex, Sierra Nevada, California, USA

Abstract The chemical and isotopic characteristics of a solidified pluton represent the integration of magmatic and sub-solidus processes operating across a range of spatial and temporal scales during pluton construction, crystallization, and cooling. Disentangling these processes and understanding where chemical and isotopic signatures were acquired requires the combination of multiple tools tracing processes at different time and length scales. We combine whole-rock oxygen and Sr-Nd isotopes, zircon oxygen isotopes and trace elements, and mineral compositions with published high-precision U-Pb zircon geochronology to evaluate differentiation within the bimodal Guadalupe Igneous Complex, Sierra Nevada, California (USA). The complex was constructed in ~300 k.y. between 149 and 150 Ma. Felsic magmas crystallized as centimeter- to meter-sized segregations in gabbros in the lower part of the complex and as granites and granophyres structurally above the gabbros. A central mingling zone separates the mafic and felsic units. Pluton-wide δ18O(whole-rock), δ18O(zircon), and Sr-Nd isotopic ranges are too large to be explained by in situ, closed-system differentiation, instead requiring open-system behavior at all scales. Low δ18O(whole-rock) and δ18O(zircon) values indicate assimilation of hydrothermally altered marine host rocks during ascent and/or emplacement. In situ differentiation processes operated on a smaller scale (meters to tens of meters) for at least ~200 k.y. via (1) percolation and segregation of chemically and isotopically diverse silicic interstitial melt from a heterogeneous gabbro mush; (2) crystal accumulation; and (3) sub-solidus, high-temperature, hydrothermal alteration at the shallow roof of the complex to modify the chemical and isotopic characteristics. Whole-rock and mineral chemistry in combination with geochronology allows deciphering open-system differentiation processes at the outcrop to pluton scale from magmatic to sub-solidus temperatures over time scales of hundreds of thousands to millions of years.

Restrictions on gold mineralization by zircon oxygen fugacity from the Paleozoic-Mesozoic magmatic rocks in the Zhangjiakou district, northern margin of the North China Craton

Restrictions on gold mineralization by zircon oxygen fugacity from the Paleozoic-Mesozoic magmatic rocks in the Zhangjiakou district, northern margin of the North China Craton

Mantle-like to low oxygen isotopes in zircon from the mid-Cretaceous high-silica granites reveal unweathered basement recycling along the present coastal area of SE China

Zircon oxygen isotope compositions can provide potential constraints on the origin of granitic magmas. In this work, we report new data of zircon UPb dating, trace elements and HfO isotopes for two types of mid-Cretaceous high-silica granites from Zhoushan archipelago in Zhejiang Province, SE China. The in-situ zircon data are carefully screened for radiation damage and post-magmatic alteration. The analyzed magmatic zircon grains indicate that the Zhoushan calc-alkaline granites (ZCAG; 101–92 Ma) have mantle-like δ18O values of 5.29–5.88 ‰, in contrast to the Zhoushan peralkaline granites (ZPAG; 91–89 Ma) with relatively low δ18O of 4.42–4.6 ‰. The slight decreases in δ18O and εHf(t) from zircon center to periphery of both groups suggest that they may have consistent oxygen isotopic compositions in their parental magma sources and have gone through assimilations to hydrothermally altered wall rocks in the shallow crust. The mantle-like δ18O values in zircon are widespread in the Cretaceous felsic rocks in the present coastal area of SE China, which, in combination Hf isotopes, indicates the possible existence of a buried unweathered Proterozoic basement in the eastern part of the Cathaysia Block. This work highlights the role of deep crustal magma sources, assimilation and post-magmatic radioactive damage on the formation of mantle-like to low δ18O signals in zircons, and has fundamental implications for understanding the formation of widespread mid-Cretaceous felsic rocks along the present coastal area of SE China.

Spatial–temporal evolution, zircon Hf-O isotope characteristics of Yanshanian magmatism and their control on ore deposits in the southeast coast of China

The southeast coast of China (SCC) is an essential component of the Circum Pacific Tectonic Metallogenic Domain with huge amount of Yanshanian magmatic rocks and related Cu-Au-Mo-W-Sn deposits. The relationship between regional deep crust component and mineralization is still not very clear. In this study, we present 27 new zircon U-Pb and Lu-Hf isotopic, 111 whole-rock major and trace element, and 11 zircon oxygen isotopic data for Yanshanian granitoid from the SCC, combining with data from literature, to display the spatial–temporal evolution of the granitoid, particularly to trace the components of the deep crust, and to delineate the crustal architecture by Hf isotopic mapping. A total of 295 zircon U–Pb ages show four phases (194 to 184, 176 to 153, 153 to 124, and 122 to 80 Ma) of magmatic rocks. These rocks characterized by continental margin arc magma were formed during the Paleo-pacific subduction and rollback. Zircon Hf isotopic mapping of these granitoids yield three Hf isotopic provinces (I, II, III), which distributed successively from the Interior Cathaysia Block (ICB) to the Coastal Cathaysia Block (CCB). Province III is the oldest, followed by province II and province I. These provinces combining with zircon O isotopic data display that the ICB is dominated by old deep crust (TDMC = 1.85 – 1.60 Ga) with a few juvenile crust, the average εHf (t) changes from -11.5 to -7.1, δ18O = 6.68 – 8.84 ‰, while the CCB is dominated by juvenile crust (TDMC= 1.35 – 1.10 Ga) with a few old deep crust, with the average εHf (t) = -3.4 to + 4.7, δ18O = 5.52 – 7.78 ‰. However, the deep crust composition along the Zhenghe-Dapu fault is complex, which is probably due to the strong crust-mantle interaction. The Hf isotopes mapping reveals temporal-spatial correlations between the composition of deep crust and spatial distribution of ore deposits, demonstrating that the architecture, nature, and composition of the crust controlled mineralization and the distribution of ore deposits. The porphyry Cu-Au deposits are exclusively located in regions with juvenile crust, granite-related W-Sn deposits cluster in the oldest crustal regions or developed along the margin of the old crustal block. This study suggests that the deep crust component can be imaged by Hf isotope mapping and it can provide significant information on mineralization with deep crust component and architecture and on strategic ore-prospecting in a region.

Bimodality in zircon oxygen isotopes and implications for crustal melting on the early Earth

Zircons from the oldest dated felsic crust, the Acasta Gneiss Complex, Canada, provide key information that may help understand the generation of crust on our nascent planet. When screened to eliminate grains with secondary alteration by measuring relative hydration (Δ16O1H/16O), primary ≥ 3.99 Ga zircon cores show δ18O of 5.88 ± 0.15 ‰, at the extreme upper (heavy) range for mantle values. Another early (≥3.96 Ga) zircon component indicates distinctly different, primary light δ18O values (δ18O ≤ 4.5 ‰). This bimodality in ancient zircon oxygen isotopes implies partial melting of both deep (lower crustal) and shallower (near surface) source rocks, responsible for felsic crust production on the early Earth. A similar bimodality in zircon δ18O is recognised in data from other ancient cratons, albeit at different times. Although alternative (uniformitarian) interpretations may also satisfy the data, the tempo of this bimodality matches models of planetary high-energy impact flux, consistent with a fundamental role for bolide impacts in the formation of crustal nuclei on the early Earth.

Mechanisms for generating elevated zircon δ18O in Archean crust: Insights from the Saglek-Hebron Complex, Canada

The Saglek-Hebron Complex (northern Labrador, Canada) is a polymetamorphic terrane preserving felsic crustal rocks as old as 3.87 Ga. Crustal rocks of this age are rare and offer opportunities to interrogate how Earth's earliest continent forming processes may have differed from the modern plate tectonic regime. Oxygen isotope ratios (δ18O) in primary crystalline zircon are strongly affected by the incorporation of supracrustal materials during magmatism and can provide useful information about the character of early crustal reworking events. While zircon δ18O signatures >+6.4 ‰ indicate the incorporation of supracrustal material into the source of crustal anatexis, questions remain regarding the volumetric scale, sources, and processes by which supracrustal and magmatic mixing occurred during the Archean. Here, we present 271 zircon in-situ oxygen isotope analyses for a suite of seven Saglek-Hebron granitoids emplaced between 3.87 and 2.79 Ga in age, significantly expanding the temporal and lithologic diversity of the magmatic SHC zircon δ18O record. Collected from carefully characterized grain domains, primary zircon δ18O values range from 5.0 to 8.4 ‰ and include some of the highest igneous Archean zircon oxygen isotope ratios recorded to date. Leveraging an integrated workflow for identifying preserved zircon geochemistry, and correlating our new data with previous information from zircon Hf and whole-rock 142Nd/144Nd isotopes, we identify three periods of contribution from high-δ18O supracrustal material to crustal melts during reworking events in the SHC at 3.63, 3.33, and 2.79 Ga. Our work points towards repeated episodes of interaction between a maturing surface environment and magmatism from 3.6 Ga onwards at this locality.

Identifying crustal contributions in the Patagonian Chon Aike Silicic Large Igneous Province

The volcanic rocks of the Chon Aike Silicic Large Igneous Province (CASP) are recognized as magmas dominantly produced by crustal anatexis. Investigating the zircon of the CASP provides an opportunity to gain further insight into geochemical and isotopic differences of the potential magmatic sources (i.e., crust versus mantle), to identify crustal reservoirs that contributed to the felsic magmas during anatexis, and to quantify the contributions of the respective sources. We present a combined zircon oxygen and hafnium isotope and trace element dataset for 16 volcanic units of the two youngest volcanic phases in Patagonia, dated here with LA-ICP-MS U–Pb geochronology at ca. 148–153 Ma (El Quemado Complex, EQC) and ca. 159 Ma (western Chon Aike Formation, WCA). The EQC zircon have 18O-enriched values (δ18O from 7 to 9.5‰) with correspondingly negative initial εHf values (− 2.0 to − 8.0). The WCA zircon have δ18O values between 6 and 7‰ and εHf values ranging between − 4.0 and + 1.5. Binary δ18O-εHf mixing models require an average of 70 and 60% melt derived from partial melting of isotopically distinct metasedimentary basements for the EQC and WCA, respectively. Zircon trace element compositions are consistent with anatexis of sedimentary protoliths derived from LIL-depleted upper continental crustal sources. The overlap between a high heat flux environment (i.e., widespread extension and lithospheric thinning) during supercontinental breakup and a fertile metasedimentary crust was key in producing voluminous felsic volcanism via anatexis following the injection and emplacement of basaltic magmas into the lower crust.

Reconstructing the evolution of an ancient continental arc: Implications from the temporally-spatially related shoshonitic to calc-alkaline intrusive magmatism in the North China Craton

Coeval shoshonitic and calc-alkaline to high-K calc-alkaline rock series were discovered in the eastern North China Craton (NCC). Here, we report zircon and titanite UPb dating, zircon oxygen isotopic, whole-rock major and trace element and SmNd isotopic data for these rocks. Zircon and titanite UPb geochronology suggests that the coeval shoshonitic to calc-alkaline mantle-derived magmas from the Jinan terrane were emplaced at ∼2.5 Ga and recorded multi-phases of metamorphic imprints. The shoshonitic series in Group I show higher K2O, but in contrast, the calc-alkaline to high-K calc-alkaline series (Group II) are characterized by higher Na2O. The two groups have enriched light rare earth elements (LREE) and depleted/nearly flat heavy rare earth elements (HREE). They also show negative anomalies in some HFSE and positive anomalies in LILE. Therefore, the geochemical data, SmNd and O isotopes included, show that the Jinan shoshonitic to calc-alkaline magmas were generated by melting of the metasomatized mantle at an ancient continental arc. Distinct geochemical features possibly suggest different mantle source features (metasomatic agents). The elevated zircon δ18O values imply that the weathering was significant during the end of Archean. In addition, the crustal reworking or intra-crustal recycling process played an important role in the continental crust evolution. The low-δ18O magmas documented here possibly indicate high-temperature water-rock interaction that occurs between continental crust and meteoric water. This study represents an example of co-existed shoshonitic and calc-alkaline mantle-derived magma derived from the melting of metasomatized mantle above an ancient subduction zone. Similar coeval associations of shoshonitic to calc-alkaline mantle-derived rocks, in combination with high-P granulites and crust-derived granites, may be used to constrain the ancient subduction-collisional belts.

Petrogenesis and Geodynamic Evolution in the Northern Westfjords, Iceland, Elucidated by Iceland's Oldest Silicic Rocks

AbstractIceland's oldest silicic rocks provide unique insight into the island's early crustal evolution. We present new zircon U‐Pb ages bolstered with zircon trace element and isotopic compositions, and whole rock Nd, Hf, and Pb isotope compositions, from three silicic magmatic centers—Hrafnsfjörður, Árnes, and Kaldalón—to understand the petrogenesis of large silicic volcanic centers in the northern Westfjords, Iceland. Our data confirm Hrafnsfjörður as the oldest known central volcano in Iceland (∼14 Ma) and establish an older age for Árnes (∼13 Ma) than previously estimated. We also report the first U‐Pb zircon dates from Kaldalón (∼13.5 Ma). Zircon oxygen isotope compositions range from δ18O∼+2 to +4‰ and indicate involvement of a low‐18O component in their source magmas. Hrafnsfjörður zircon Hf (mean sample εHf ∼ +15.3–16.0) and whole rock Hf and Nd (εHf = +14.5 to +15; εNd = +7.9 to +8.1) isotopic compositions are more radiogenic than those from Árnes (zircon sample εHf ∼ +11.8–13; whole rock εHf = +12.8 to +15.1; εNd = +7.3 to +7.7), but Hrafnsfjörður whole rock Pb isotope compositions (208/204Pb = 37.95–37.96; 206/204Pb = 18.33–18.35) are less radiogenic than those from Árnes (208/204Pb = 38.34–38.48; 206/204Pb = 18.64–18.78). Kaldalón has zircon Hf isotope compositions of εHf∼+14.8 and 15.5 (sample means). These age and isotopic differences suggest that interaction of rift and plume, and thus the geodynamic evolution of the Westfjords, is complex. Isotopic compositions of Hrafnsfjörður and Árnes support involvement of an enriched mantle (EM)‐like mantle component associated with a pulsing plume that resulted in variable spreading rates and magma fluxes and highlight the heterogeneity of the Icelandic mantle.

Late Neoarchean crust–mantle interaction and tectonic implications in western Shandong Province, North China Craton: Evidence from a granodiorite pluton and associated magmatic enclaves

This study presents original data on the microstructure, mineralogy, whole–rock geochemistry, and isotopes of a Late Neoarchean granodiorite pluton and associated mafic microgranular enclaves (MMEs) in western Shandong Province of the eastern part of the North China Craton (NCC). The MMEs hosted in the granitic pluton are more mafic, and amphibole and biotite are the predominant mafic minerals. The sharp contacts and fine–grained textures of the MMEs indicated a rapid quenching process during a magma mingling event. Zircon and titanite UPb dating indicated that the host granodiorite pluton formed at circa 2546 Ma, and the MMEs formed at approximately 2538 Ma. The dating results indicated a crust–mantle interaction. Geochemically, the host pluton has high silica contents (SiO2 = 67.68–68.51 wt%), Mg# values (51–53) and low Aluminum Saturation Index ratios (A/CNK = 0.92–0.95), which are indicative of I–type granitic affinity. Moreover, they show arc–type trace element features characterized by enrichment of light rare earth elements (LREEs) and large ion lithophile elements (LILEs) (e.g., Cs, Rb, K, and Pb), but depletion in high field strength elements (HFSEs) (e.g., Nb, Ta, P, and Ti). In contrast, the MMEs have lower silica contents (SiO2 = 52.07–56.03 wt%), but higher Mg# values (56–68) and Cr, Ni and Cu contents of 454–633, 159–225 and 98.3–207 ppm, respectively, corresponding to a mantle component. Similar to the host pluton, the MMEs show enrichment of LREEs and LILEs, but depletion of HFSEs, reflecting an arc–type magma origin. Isotopically, the host granodiorite and MMEs both have relatively depleted NdHf isotopic compositions, with εNd(t) values of −0.67–1.22 and − 0.31–1.89, and εHf(t) values of 5.63–2.03 and − 0.18–4.48, respectively. Zircon oxygen isotopes reveal that the host granodiorite and MMEs have slightly higher oxygen isotopes than the normal mantle zircon (5.3‰), with mean δ18O values of 6.35‰ and 6.81‰, respectively, indicating assimilation of minor supracrustal materials in the magma source. However, a combination of Nd–Hf–O isotopes suggests that the MMEs haveslightly enriched isotopic compositions than the host granodiorite pluton, suggesting a “reversed isotope” feature. This important finding also enlightens that “reversed isotope” phenomenon represented magma mingling between isotopically relatively enriched mafic and relatively depleted felsic magmas. Furthermore, the Ce4+/Ce3+ ratios in zircon from the host granodiorite and MMEs indicated a low oxygen fugacity, with mean values of 24.25 and 39.69, respectively. Although the host granodiorite and MMEs have the similar oxygen fugacity ranges, the MMEs have high Cu concentrations of 98.3–207 ppm (mean value = 151 ppm), indicating a Cu–rich magma source. Integrating the petrogenesis of the Late Neoarchean granodiorite pluton and associated MMEs, it is inferred that the host granodiorite pluton was derived from partial melting of mafic lower crust with minor insignificant ancient materials, and the MMEs were derived from partial melting of depleted mantle metasomatized by sulfur–rich sediment melts/fluids (chalcophile element). Tectonically, our samples reveal an affinity with an arc in a syn–collisional setting. Together with regional rock assemblages, we suggest that the onset of plate tectonics (subduction) was to occur by the end of Neoarchean in the NCC.

Identification of the early cretaceous granitic pluton and tectonic implications in the middle gangdese belt, southern tibet

The Gangdese magmatic belt of southern Tibet is an ideal place to study Neo-Tethyan subduction, continental crustal growth and reworking. However, there are still controversies with regard to the evolution of the Neo-Tethys Ocean, the magma source and the detailed diagenetic processes of igneous rocks in the Gangdese belt. The Early Cretaceous magmatic exposures are sporadic in the Gangdese magmatic belt. Thus the finding of the new exposure is key to understanding the scenarios of the Neo-Tethys Ocean and geological background of southern Tibet during the Early Cretaceous. In this contribution, we undertook systematic geochronology, whole-rock geochemistry and zircon Lu-Hf isotopic studies on a newly identified granitic pluton in the middle Gangdese belt (Quesang area), southern Tibet. The results show that zircon U-Pb dating of three representative samples yielded a weighted age of 120 ± 1.4 Ma, 117.3 ± 2.5 Ma and 114.0 ± 1.3 Ma, respectively, which indicate the emplacement and crystallization age belonging to the Aptian stage of the Early Cretaceous in response to the northward subduction of the Neo-Tethyan oceanic lithosphere beneath the Lhasa terrane. In situ zircon Lu-Hf isotopic analyses indicate that ƐHf(t) values of the studied granitic pluton are predominantly positive ranging from 7.2 to 11.4, and one zircon shows negative ƐHf(t) value (−6.26), implying that a small amount of ancient continental crustal materials might have participated in the magma evolution. Geochemically, the granite samples are enriched in large ion lithophile elements (LILE) and light rare earth elements (LREE), but depleted in heavy rare earth elements (HREE), indicating arc-type geochemical characteristics or subduction-related tectonic setting. In addition, combined with mineral assemblages, zircon Lu-Hf isotopic features and low molar Al2O3/(CaO+Na2O+K2O) (A/CNK) ratios of 0.91–1.10, the studied samples show a close affinity with I-type granites. Moreover, zircon oxygen fugacity results show that Ce4+/Ce3+ values range from 185 to 12, with a mean value of 78, indicating a low oxygen fugacity setting similar to the Chile ore-barren granitic plutons. In combination with published data, we argue that the Gangdese magmatic belt may have developed continuous magmatism (145–105 Ma), and the notion of magmatic lull might deserve more consideration during the Early Cretaceous. In this study, the Early Cretaceous granitic pluton might be the result of the northward subduction of Neo-Tethys oceanic lithosphere beneath the Lhasa terrane at a normal angle.

Cretaceous basalt-andesite sequence in the Southern Pamir: arc—back-arc architecture at the Pamir Plateau genetically related to the northward flat subductions of the Neo-Tethys Ocean

The Pamir-Karakorum is one of the most important regions for our understanding the Tethys evolution. Although it is commonly known that the northward subduction of the Neo-Tethys Ocean induced the formation of the magmatic arc in Southern Pamir, the temporal-spatial configuration of the arc—back-arc during the Neo-Tethys evolution remains unclear. In this study, we report sedimentary feature, petrography, zircon U Pb ages and Hf O isotope compositions as well as bulk-rock and mineral geochemistry of the well-preserved Cretaceous volcanic sequence in Chinese Wahan Corridor at South Pamir. The volcanic sequence is mainly composed of phenocrysts- bearing basalt- andesites with minor rhyolite and volcaniclastic rock. Zircon U Pb ages reveal the basalt-andesite sequence erupted at 100–98 Ma. Bulk-rock geochemistry defines their potassic calc-alkaline signature and both their rock association and elemental geochemistry share most features of the continental arc volcanic sequences. On the other hand, they have variably enriched Nd isotope compositions with ε Nd (t) varying from −5.9 to −9.6, coupled with their enriched zircon Hf isotope signature with ε Hf (t) between −13 to −8. Whole-rock geochemistry and zircon oxygen isotope compositions (average δ 18 O = 7.74 ± 0.14) demonstrate that the primitive magma of the basalt-andesites were derived from partial melting of a metasomatized sub-continental lithospheric mantle and underwent variable assimilation fractional crystallization. Late Jurassic to Cretaceous volcanic-sedimentary sequences and coeval voluminous arc-like granodiorite and granites are widely distributed along the Southern Pamir. In the Central Pamir and further north, late Jurassic to Cretaceous sequences resemble features of back-arc basins. Taken together, we suggest that a northward low-angle or flat subduction of the Neo-Tethys Ocean along the Shyok zone was geodynamically related to the formation of the broad magmatic arc in South Pamir-Karakorum and the back-arc basins north of the South Pamir. • Arc-like Cretaceous basalt-andesite sequence in Southern Pamir (SP) erupted at ~100 Ma. • Architecture of the late Jurassic-Cretaceous arc-back-arc at Pamir was constructed. • Flat subduction of the Neo-Tethys Ocean produced the Cretaceous igneous rocks in SP.

Whole-rock geochemistry and zircon O-Hf isotope compositions of ca. 2.35 Ga strongly peraluminous granites: Implications for increase in zircon δ18O values during the Paleoproterozoic

Zircon oxygen isotope ratios have been used to trace the incorporation of sedimentary rocks into magmas. The dramatic increase in maximum zircon δ18O values in the Paleoproterozoic observed in global databases coincides with changes in surface environments (e.g., the rise of subaerial and oxidative weathering), implying a connection between elevated zircon δ18O and these changes. Zircon δ18O between 2.5 and 2.2 Ga, however, is relatively under-constrained owing to limited available data in this age range. To augment data from this critical time period and understand potential causes for the elevated zircon δ18O values, we report U-Pb zircon ages and δ18O values of zircon, as well as, whole-rock major and trace element geochemistry of Paleoproterozoic strongly peraluminous granites (SPGs) from the southwestern margin of the Yangtze Block (China). Our geochronological data demonstrate that these SPGs crystallized at ∼2.35 Ga and that inherited zircon with ages of 2428–2721 Ma are present in these granites, indicating the source rocks of these granites were deposited, subsequently metamorphosed, and partially melted between 2.43 and 2.35 Ga. Synmagmatic zircon from samples dated in this study have εHf(t) values of −6.4 to −0.9 and high δ18O values of 7.6–9.9‰, elevated above the maximum value observed in Archean zircon (∼7‰). These granites can be divided into two groups based on whole-rock geochemistry. Both Group 1 and Group 2 granites were derived from a similar high δ18O, metapelitic source, but were generated by dehydration melting and hydrous melting, respectively. Our results demonstrate that the fine-grained sedimentary rocks from which the SPGs were derived had relatively high δ18O (as compared to older sedimentary rocks) by 2.43–2.35 Ga. The depositional time interval of the high-δ18O sedimentary sources for SPGs studied here coincides with the emergence of continental crust above sea level and the Great Oxidation Event. Supporting the findings of previous studies, the contemporaneity of our dataset with these changes in Earth’s surface environments suggests that subaerial and potentially oxidative weathering contributed (at least partially) to the elevation of δ18O of fine-grained sedimentary rocks. Recycling of these high-δ18O sedimentary rocks into magmas contributed to the dramatic change in δ18O of magmatic zircon in the earliest Paleoproterozoic. In addition, although this study is focused on a single locality, our results suggest that the abrupt shift observed in global zircon δ18O data sets likely occurred by 2.35 Ga. Last, a literature compilation of zircon δ18O data from SPGs suggested that zircon δ18O values may have also experienced a stepwise increase in the Neoproterozoic to Phanerozoic from 12 to 14‰. The coincidence of these increases in zircon δ18O values with global oxygenation events suggests that atmospheric oxygenation may have contributed to the increase in δ18O of sedimentary rocks.

Reconstruction of a volcano-sedimentary environment shared by the Porongos and Várzea do Capivarita complexes at 790 Ma, Dom Feliciano Belt, southern Brazil

This work investigates the pre-collisional (before ca. 650 Ma) history of the Dom Feliciano Belt in southernmost Brazil through geochronological and zircon oxygen isotope study. U–Pb SHRIMP dating of two orthogneiss samples from the Várzea do Capivarita Complex and one metarhyolite sample from the Porongos Complex yielded crystallisation ages of 786 ± 5 Ma, 780 ± 10 Ma and 787 ± 5 Ma, respectively. The mean oxygen isotope values calculated for the ca. 790 Ma zircon cores from the orthogneisses are 8.41 ± 0.13‰ and 8.68 ± 0.14‰, and 8.75 ± 0.72‰ for the metarhyolite. Such values suggest that zircon crystallised in the more evolved magmas, either from the melting of host rocks and sediments or assimilation of crustal material by mantle-derived magmas. The detrital zircon population was analysed in one additional paragneiss sample from the Várzea do Capivarita Complex, and most of the values cluster at 790–750 Ma. The data spread is centred at ca. 790 Ma, which is the crystallisation age of the interleaved orthogneisses. In our interpretation, such dataset suggests a syn-volcanic origin of the paragneiss protolith and, therefore, a volcano-sedimentary origin of the Várzea do Capivarita Complex. The correspondence of geochronological data and zircon oxygen isotope values for the studied meta-igneous samples suggests that the Várzea do Capivarita and Porongos complexes have shared the same igneous history. Therefore, the samples probably represent one magmatic event at different levels of a single basin at ca. 800–770 Ma. Such results bring first-order information about the meaning of tectonic limits in this Gondwana-related belt and implications for reconstructing the pre-collisional history of the orogen.

Discrepant chemical differentiation and magmatic-hydrothermal evolution of high-silica magmatism associated with Pb–Zn and W mineralization in the Lhasa terrane

High-silica (SiO2 > 70 wt.%) granites (HSGs) are the main source of W, Sn, and rare metals. However, abundant HSGs, temporally, spatially, and genetically associated with Pb–Zn mineralization, in the Lhasa terrane (LT), provided an ideal opportunity to study the key factors responsible for Pb–Zn enrichment, instead of W–Sn enrichment. Here we contribute to this topic through U-Pb dating of zircon and garnet, and whole-rock and Sr–Nd–Hf isotopic geochemistry of ore-related quartz porphyries in the Bangbule deposit and compared these results with published data from large and giant Pb–Zn and W deposits in the LT. The magmatism-alteration-mineralization event in the Bangbule deposit was recorded by robust zircon U–Pb ages of 77.3 ± 0.9 Ma and hydrothermal garnet U–Pb ages of 75.7 ± 4.8 Ma, which is 10–15 Ma earlier than the main Paleocene metallogenic event and the first record of late Cretaceous Pb–Zn polymetallic mineralization in the LT. The late Cretaceous-Paleocene magmatism and mineralization events are a response to the subduction of Neotethyan oceanic lithosphere, which occurred as a result of the collision of the Indian and Asian plates. These HSGs related to Pb–Zn mineralization, with high total-alkalis and low magnesian contents, are enriched in Ba, Th, and Rb, but depleted in Ti, Eu, Sr, and P. They belong to either the S-type, or I-type granites. The Sr–Nd–Hf isotopic compositions of the Pb–Zn mineralized granites demonstrate that they were generated by the partial melting of Proterozoic basement with or without mantle-derived melt input. This was consistent with the postulated source of W enrichment in the LT. The Pb–Zn and W related granites have similar zircon-Ti-saturation temperatures, comparable low whole-rock Fe2O3/FeO ratios, and zircon oxygen fugacity. This indicated that the Pb–Zn–W enrichment in the high-silica magma system could be attributed to a relatively reduced magma. The Pb–Zn related HSGs, abundant quartz and feldspar phenocrysts, and weak fractionation of twin-elements in whole-rock analysis, can be used to reconstruct a model of the magma reservoir. We postulate that these features could be reproduced by silica-rich crystal accumulation in a magma reservoir, with a loss of magmatic fluids. The magma associated with W mineralization exhibited a higher level of differentiation compared to the Pb–Zn related magma; however, different groups of zircon texture with varying rare earth elements and concomitance of rare earth elements tetrad effect and high fractionation of twin-elements in whole-rock are formed by a magmatic-hydrothermal transition in highly evolved system. As the source and oxygen fugacities of the Pb–Zn and W related magmas are similar, the absence of a giant W–Sn deposit in the LT may indicate that parent magmas with a low degree of evolution and magmatic-hydrothermal transition are not conducive to their formation. This implies that the rocks that originated as highly evolved silicate-rich parent magmas, with a high degree of magmatic-hydrothermal alteration, would need to be targeted for W–Sn mineral exploration in the LT. In summary, our results emphasize that variations in chemical differentiation and the evolution of high-silica magmatic-hydrothermal systems can lead to differences in Pb–Zn and W enrichment. This has implications for the evaluation of the mineral potential of high-silica granites and hence their attractiveness as targets for mineral exploration.

Oceanic Zircon Records Extreme Fractional Crystallization of MORB to Rhyolite on the Alarcon Rise Mid-Ocean Ridge

Abstract The first known occurrence of rhyolite along the submarine segments of the mid-ocean ridge (MOR) system was discovered on Alarcon Rise, the northernmost segment of the East Pacific Rise (EPR), by the Monterey Bay Aquarium Research Institute in 2012. Zircon trace element and Hf and O isotope patterns indicate that the rhyolite formed by extreme crystal fractionation of primary mid-ocean ridge basalt (MORB) sourced from normal to enriched MOR mantle with little to no addition of continental lithosphere or hydrated oceanic crust. A large range in zircon ɛHf spanning 11 ɛ units is comparable to the range of whole rock ɛHf from the entire EPR. This variability is comparable to continental granitoids that develop over long periods of time from multiple sources. Zircon geochronology from Alarcon Rise suggests that at least 20 kyr was needed for rhyolite petrogenesis. Grain-scale textural discontinuities and trace element trends from zircon cores and rims are consistent with crystal fractionation from a MORB magma with possible perturbations associated with mixing or replenishment events. Comparison of whole rock and zircon oxygen isotopes with modeled fractionation and zircon-melt patterns suggests that, after they formed, rhyolite magmas entrained hydrated mafic crust from conduit walls during ascent and/or were hydrated by seawater in the vent during eruption. These data do not support a model where rhyolites formed directly from partial melts of hydrated oceanic crust or do they require assimilation of such crust during fractional crystallization, both models being commonly invoked for the formation of oceanic plagiogranites and dacites. A spatial association of highly evolved lavas (rhyolites) with an increased number of fault scarps on the northern Alarcon Rise might suggest that low magma flux for ~20 kyr facilitated extended magma residence necessary to generate rhyolite from MORB.