Zirconia Composites Research Articles

Tectonomagmatic evolution of southwestern Laurentia: Insights from zircon U-Pb geochronology and hafnium isotopic composition of the Red Bluff Granite Suite, west Texas, USA

AbstractWe provide laser ablation–multicollector–inductively coupled plasma–mass spectrometry (LA-MC-ICP-MS) and high-precision chemical abrasion–isotope dilution–thermal ionization mass spectrometry (CA-ID-TIMS) U-Pb ages and Hf isotopic compositions of zircons from the Red Bluff Granite Suite and mafic dikes in the Franklin Mountains of El Paso, Texas, USA. Granitoids exposed in the Franklin Mountains were previously divided into five magmatic stages based on cross-cutting relationships. Major and trace element compositions showed that these granitoids are ferroan, alkaline, and A2 type. Homogeneity in the whole-rock geochemistry suggests that the granite stages are genetically related and share similar petrogenetic histories. Weighted mean zircon 206Pb/238U dates from the older magmatic stage 1 alkali-feldspar quartz syenite and stage 2 alkali-feldspar granite are 1112.36 ± 0.35 and 1112.46 ± 0.37 Ma, respectively. The weighted mean εHf(t) values varying from +5.3 to +7.2 are similar to those of other regional ca. 1.1 Ga magmatic rocks throughout southwestern Laurentia. Geochemical characteristics, petrological modeling, and enriched Hf isotopic composition suggest fractional crystallization of a basaltic magma that was produced by melting of an enriched mantle reservoir. However, zircon inheritance ages of ca. 1.3 Ga and 1.26–1.15 Ga are consistent with a minor contribution from felsic crustal basement. Our data and regional geology are consistent with a post-collisional slab break-off that facilitated asthenospheric upwelling and partial melting of the enriched mantle, possibly subcontinental lithospheric mantle, extending from Llano Uplift, Texas, in the southeast to California to the northwest. Magma thus generated upon differentiation produced ferroan and A-type granitoids.

Translucent and Highly Toughened Zirconia Suitable for Dental Restorations

Background: There is a limit to improving the characteristics of zirconia with only one kind of stabilizing element such as yttrium. The purpose of this study is to systematically evaluate the effects of various co-doped elements on mechanical and optical properties and to develop a novel composition of zirconia with enough properties to apply to dental restorations. Methods: Forty-four kinds of zirconia were prepared by combining trivalent cations yttrium (Y) and ytterbium (Yb), and pentavalent cations niobium (Nb) and tantalum (Ta) oxide as stabilizers. The combined contents ranged from 0 to 5.6 mol% for Y2O3, 0 to 4.2 mol% for Yb2O3, 0 to 1.5 mol% for Nb2O5, and 0 and 1.2 mol% for Ta2O5. These specimens were determined for fracture toughness and opacity. X-ray diffraction studies were undertaken to evaluate the microstructural change. Results: The present study revealed that adding of the trivalent cations Y and Yb reduced fracture toughness and opacity, whereas the addition of pentavalent cations Nb and Ta to zirconia stabilized with trivalent cations increased both properties. There was no clear difference in the effects of Y and Yb, Nb, and Ta. Conclusions: Considering many factors, the following composition is optimal: 3–4.2 mol% Y2O3 and/or Yb2O3 stabilized zirconia with up to 1.5 mol% Nb2O5 has sufficiently high fracture toughness values and sufficiently high translucency suitable for dental restorations.

Morphology, Structure, and Composition of Zircon from Metasandstones of the Alkesvozhskaya Sequence (Polar Urals)

A description of the features of morphology, internal structure, and analysis results of Th/U and Zr/Hf ratios in zircons from sandstones of the gold-bearing Alkesvozhskaya sequence, located at the basement of the Paleozoic section in the Subpolar Urals, is presented. It has been established that most of the studied zircons are primary igneous grains of the first weathering cycle. The detrital zircon source was probably in formations close in age, underlying or located nearby felsic and basic volcanics of igneous complexes of different stages of formation of Timanides-protouralides, associated granitoids, and intrusive mafic formations. Small part of well-rounded zircon Pre-Riphean grains can be redeposited from the Riphean metasedimentary formations, which, in turn, inherited it from the rocks of the ancient basement of the East European Platform.

Циркон как источник генетической информации в верхнерифейских терригенных отложениях Южного Тимана

Zircon is an important source of genetic information. The purpose of the research is a detailed study, identification of diagnostic features, and determination of the evolution of the composition of zircon, which will make it possible to establish the sources of clastic material and the conditions for the formation of the paleontologically mute terrigenous Dzhezhim Formation on the Dzhzhimparma Rise (Southern Timan). The article presents the results of the study of zircon from the Upper Proterozoic metasedimentary deposits of the South Timan by Raman spectroscopy. According to morphological features, chemical composition, internal structure and degree of crystallinity, four types of zircon have been distinguished. The Raman spectra of all morphological types of the studied mineral was surveyed. A comparative analysis of the Raman characteristics showed that the first type is characterized by the highest degree of crystallinity, the third type is characterized by the minimum, and the second type occupies an intermediate position. The fourth type is a unique highphosphorus zircon, the nature of its spectra reflects the presence of Y, P, REE, and other impurity elements, and also indicates its metamictization as a result of radiation damage to the structure. Morphological features, differences in the chemical composition and characteristics of the Raman spectra of the distinguished types of zircon indicate the difference in the sources from which they entered the sedimentary rock. The source of type I zircon could be felsic igneous rocks. Type II and III zircons are probably of metamorphogenic origin. The formation of the modern composition and appearance of zircons of the fourth type, the formation of which is associated with a high-temperature magmatic source, is due to multiphase transformations in hydrothermal-metamorphic and epigenetic processes. We believe that type IV zircons have the longest history of existence. This is evidenced by their high metamict, i.e., the destruction of the crystal lattice under the action of U and Th radiation, which depends on their number and the age of zircon grains. It is known that the age of zircon of the Dzhezhim Formation is pre-Upper Riphean; during its existence, the mineral was repeatedly subjected to various external influences that changed the parameters of its crystal structure.

Effect of sintering procedures on optical properties, chemical composition, and grain size of monolithic zirconia ceramic at different thicknesses after hydrothermal aging: An in vitro study.

The purpose of the present study was to examine the optical properties, chemical composition, and grain size (GS) of monolithic zirconia (MZ) ceramic at different thicknesses sintered using different procedures after hydrothermal aging. An in vitro study. Forty MZ discs (0.5-mm thickness [Group-0.5] and 1-mm thickness [Group-1]; 12 mm diameter) were milled and divided according to standard (Group-ST) and speed (Group-SP) sintering procedures. All specimens were hydrothermally aged at 134°C after sintering. Translucency (TP), opalescence (OP), and fluorescence (ΔEabFNx01-FL) parameters were calculated using the color coordinates (LFNx01, aFNx01, bFNx01, respectively) of the discs. The chemical composition and the GS of the specimens were characterized using X-ray fluorescence spectroscopy and a scanning electron microscopy, respectively. TPs and ΔEabFNx01-FLs were analyzed using independent samples t-tests and Mann-Whitney U-tests while a two-way analysis of variance (ANOVA) was used for OPs. Group-1 showed significantly lower TP than Group-0.5 (P < 0.001) but a significantly higher OP (P = 0.014). Group-SP showed significantly higher OP (P = 0.00003) and ΔEabFNx01-FL (P = 0.0026) values than Group-ST without considering the thickness. Group-SP (0.29 ± 0.119 μm) had a smaller GS than Group-ST (0.306 ± 0.142 μm). Compared to Group-ST, Group-SP had a lower percentage of Y2O3 and a higher percentage of Al2O3. The effect of the sintering procedure on TP and OP of MZ was not perceived by the naked eye. The speed sintering procedure may increase Δ EFNx01ab-FL of MZ to higher values than natural teeth when compared with standard sintering. The speed sintering may cause minor changes in GS and the chemical composition of MZ.

Effect of acidic media on flexural strength and fatigue of CAD-CAM dental materials.

To investigate the effect of acidic media, including beverages and gastric fluids on flexural strength and fatigue of CAD-CAM materials. Four CAD-CAM materials (high-translucency zirconia (Ceramill Zolid HT+), lithium disilicate (IPS e-max CAD), hybrid ceramic (Vita Enamic), and nanohybrid resin composite (Grandio Blocs) were prepared and immersed in one of five media (gastric HCl, white wine, Coca-Cola, orange juice, and artificial saliva) in an incubator (37℃, 24h). Surface topography and roughness were obtained using a scanning electron microscope (SEM) and a stylus contact profilometer, respectively. Initial 3-point flexural strength was measured for half of the bars (n=20/gp) using a universal testing machine (0.5mm/min). The other bars underwent 106 cyclic fatigue loadings before measurement of residual 3-point flexural strength. Data were statistically analyzed (two-way and three-way ANOVA, Tukey's post-hoc, p<0.05). Weibull distributions were plotted for reliability analysis. Zirconia bars has the highest initial flexural strengths followed by lithium disilicate, while resin composite and hybrid ceramic groups had the lowest strength regardless of the erosive medium. Cyclic fatigue significantly reduced initial flexural strengths for all materials except for hybrid ceramic and resin composite. Weibull moduli were the highest for zirconia, lithium disilicate and resin composite and lowest for hybrid ceramic. Erosive media significantly changed surface roughness of CAD-CAM materials except for zirconia and resin composite without jeopardizing the flexural strength of the CAD-CAM materials. Despite the higher flexural strengths for zirconia and lithium disilicate, resin composite and hybrid ceramic were more resistant to cyclic fatigue.

U-Pb ages and REE compositions of zircon in megacrystic phengite-bearing quartz vein from the Lanterman Range, northern Victoria Land, Antarctica

U-Pb ages and REE compositions of zircon in megacrystic phengite-bearing quartz vein from the Lanterman Range, northern Victoria Land, Antarctica

Esthetic solutions with layered zirconia prostheses: A case series

One of the major clinical challenges in the rehabilitation of anterior teeth is achieving natural looking restorations for improper shape, size of the existing teeth, irregular gingival contour and unaesthetic shades. Increasing demand by patients for aesthetic and metal-free restorations has resulted in all-ceramic restorations such as dental zirconia that offer optimal aesthetics with desirable mechanical properties. A case series of clinical reports of layered zirconia fixed dental prostheses for anterior teeth is described. Prosthetic rehabilitation of endodontically treated and vital abutments are described and the influence of zirconia composition, design, layering technique, shade selection, occlusion and clinical challenges in each of the clinical conditions are discussed. Choice of zirconia composition, framework design and shade selection in layered zirconia prosthesis is influenced by abutments in layered zirconia prosthesis.

Antibacterial and Proliferative Effects of NaOH-Coated Titanium, Zirconia, and Ceramic-Reinforced PEEK Dental Composites on Bone Marrow Mesenchymal Stem Cells.

Several metallic and polymer-based implants have been fabricated for orthopedic applications. For instance, titanium (Ti), zirconia (Zr), and polyetheretherketone (PEEK) are employed due to their excellent biocompatibility properties. Hence, the present study aimed to compare the functional and biological properties of these three biomaterials with surface modification. For this purpose, Ti, Zr, and ceramic-reinforced PEEK (CrPEEK) were coated with NaOH and tested for the biological response. Our results showed that the surface modification of these biomaterials significantly improved the water contact, protein adhesion, and bioactivity compared with uncoated samples. Among the NaOH-coated biomaterials, Ti and CrPEEK showed higher protein absorption than Zr. However, the mineral binding ability was higher in CrPEEK than in the other two biomaterials. Although the coating improved the functional properties, NaOH coating did not influence the antibacterial effect against E. coli and S. aureus in these biomaterials. Similar to the antibacterial effects, the NaOH coating did not contribute any significant changes in cell proliferation and cell loading, and CrPEEK showed better biocompatibility among the biomaterials. Therefore, this study concluded that the surface modification of biomaterials could potentially improve the functional properties but not the antibacterial and biocompatibility, and CrPEEK could be an alternative material to Ti and Zr with desirable qualities in orthopedic applications.

Destruction of the lower crust beneath the North China Craton recorded by granulite and pyroxenite xenoliths

The lower crust beneath the North China Craton (NCC) was transformed during the craton destruction in the Mesozoic, however, the transformation processes are yet to be fully understood. Compositional and geochronological variations of granulite and pyroxenite xenoliths provided insights into the nature of the lower crust before and after the craton destruction. In this study, we summarized the latest results of geochemistry and zircon geochronology coupled with Hf-O isotopes from granulite and pyroxenite xenoliths hosted by Phanerozoic igneous rocks in NCC. Comparing previous studies on the granulite terranes and adakitic rocks of NCC, we aim to discuss the destruction processes of lower crust beneath the NCC. The granulite and pyroxenite xenoliths of NCC were divided into two and three groups, respectively, based on the differences of geochemical features. Group I granulite xenoliths from the NCC have silicic-basic compositions, with metamorphic ferrosilite. The Group I granulite xenoliths show relatively lower Mg# values of pyroxenes and whole-rock than that of the Group II granulite xenoliths, and enrichments of light rare earth elements and Sr-Nd isotopic compositions. Their zircons display Archean-Phanerozoic ages with three peaks of Neoarchean, Paleoproterozoic, and Mesozoic. Generally, Group I granulite xenoliths show close affinities to the granulite terranes of the NCC in terms of the major and trace elements and Sr-Nd isotopic compositions, with a consistent Archean-Proterozoic evolutionary history. However, Group I granulite xenoliths have abundant Phanerozoic zircons with variable Hf isotopic compositions from depleted to enriched, which could be formed by modifications of magma underplating. Therefore, Group I granulite xenoliths represent the modified ancient lower crust beneath the NCC. The Group II granulite and Group III pyroxenite xenoliths from the NCC have similar geochemical features and are basic in compositions, with metamorphic to magmatic orthopyroxenes. The Group II granulite and Group III pyroxenite xenoliths usually show higher MgO and lower incompatible elements compositions in minerals and bulk rocks than that in the granulite terranes and Group I granulite xenoliths, but their Sr-Nd isotopic compositions fall into the fields of granulite terranes and group I granulite xenoliths. Zircons from the Group II granulite and Group III pyroxenite xenoliths are predominantly Phanerozoic with subordinate Archean-Proterozoic ages, and the Hf-O isotopic compositions of zircons are similar to those in the Group I granulite xenoliths. Additionally, the trace element compositions of Group II granulite and Group III pyroxenite xenoliths are complementary to those of the adakitic rocks from the NCC. Furthermore, the similar Sr-Nd and zircon Hf isotopic compositions among Group II granulite and Group III pyroxenite xenoliths and adakitic rocks indicate that they are cognate. Therefore, we suggest that the Group II granulite and Group III pyroxenite xenoliths could be restites left after partial melting of the ancient basic lower crust that produced voluminous adakitic rocks. In contrast, Group I and II pyroxenite xenoliths from the NCC have cumulate and reaction origins, respectively. The Group I and II pyroxenite xenoliths commonly have magmatic enstatite and show higher Mg# values and depleted Sr-Nd isotopic compositions of minerals and bulk rocks relative to that in the granulite and Group III pyroxenite xenoliths. Formation of voluminous Group I pyroxenite cumulates in the crust-mantle transition zones implies extensive magma underplating beneath the NCC during the Mesozoic-Cenozoic, which also provided exotic materials and heat for the reworking of the ancient lower crust. Therefore, the destruction of the lower crust beneath the NCC could result from continuous modifications and remelting of the ancient lower crust triggered by magma underplating. These processes led to not only the transformations of some ancient basic lower crust into granulite and pyroxenite restites but also the compositional modifications of the ancient lower crust. Consequently, the lower crust beneath the NCC showed downward rejuvenation, similar to the lithospheric mantle.

A refined Archean-Paleoproterozoic magmatic framework of the Cuoke Complex, SW China, and its implications for early Precambrian evolution of the Yangtze Block

New age data from the Cuoke Complex in southwestern Yangtze Block, integrated with published data from this region, indicate an Archean to early Paleoproterozoic magmatic history distinct from the northern Yangtze Block. Zircon cores and rims from eleven granitoids of the Cuoke Complex were analyzed by LA-ICP-MS and SHRIMP and show magmatic U-Pb ages ranging from 2850 to 2194 Ma. Combined U-Pb zircon igneous age data from the Kunming-Hainan Domain in the southwestern Yangtze Block display major magmatism ranging 3.10–3.06 Ga with a peak at ca. 3.08 Ga, 2.92–2.77 Ga with a peak at ca. 2.85 Ga and 2.4–2.1 Ga with peaks at 2.36–2.32 Ga and 2.22 Ga. This age distribution contrasts with the zircon U-Pb magmatic age data from the igneous rocks of the Kongling Domain in the northern Yangtze Block. A gap in magmatic activity in the northern domain between 2.4 and 2.2 Ga overlaps with the major peak in magmatism in the southwestern domain. Furthermore, potassic granitoids, which mark the cratonization of the two domains are more than 200 Ma years earlier in the Kongling Domain than that in the Kunming-Hainan Domain. Hf isotopic compositions of zircons from igneous rocks of the southwestern domain indicates significant juvenile crustal generation during the Mesoarchean era peaked at ca. 3.08 Ga, whereas the early Paleoproterozoic was characterized by crustal reworking and remelting. Zircon Hf isotopic compositions also reveal differences in crustal growth between the two domains. The northern domain shows a wider two-stage Hf model age range, with a peak at ca. 3.17 Ga and a subsidiary peak at ca. 3.78 Ga. Therefore, the northern domain also shows significant crustal growth in the Mesoarchean, though the age peak is about 100 Ma older compared to the southwestern domain. The Eoarchean crustal growth event recorded in the northern domain is absent in the southwestern domain. Therefore, the southwestern and northern Yangtze blocks display independent magmatic histories during the Archean and early Paleoproterozoic. The common records of late Paleo- and Mesoproterozoic tectonothermal events indicate the two domains were juxtaposed at this time, probably in association with assembly of the Nuna supercontinent.

Zircon Hf-O isotopic constraints on the origin and temporal evolution of the Toba volcanic system, Indonesia

Combined U-Pb-Hf-O isotopic analyses of zircons are useful probes to investigate the origin and temporal evolution of long-lived magma reservoirs feeding large eruptions. This study presents a complete dataset of zircon Hf-O isotopes of the latest five Toba eruptions in Quaternary. The new isotopic data differ slightly within and between eruptive units, with the majority of zircons having ε Hf values between −8 to −5 and δ 18 O values between 6 and 6.8. These Hf-O isotopic compositions of zircons were considered to inherit from an enriched and slightly heterogenous magma source. Specifically, zircons of the Oldest Toba Tuff (OTT) have rather restricted and constant Hf-O isotopes, which may crystallize from a reservoir protractedly supplied from the same magma source. Zircons of the Middle Toba Tuff (MTT) have a large range of δ 18 O values varying from ~6 to 8, with low ε Hf values extending to −14, indicating shallow-level crustal contamination. The largely negative correlations between ε Hf and δ 18 O for zircons from the MTT is indicative of contamination of high-δ 18 O crustal materials, whereas those of the positive correlations for zircons from the Youngest Toba Tuff (YTT) implies contamination of hydrothermally altered low-δ 18 O crustal materials. It is important that the Hf-O isotopes of all the zircons do not record any single batch of magma that was derived from partial melting of depleted mantle peridotites, but are consistent with an enriched and heterogenous mantle source hybridized by the subducted sediments, followed by contamination of low-δ 18 O or high-δ 18 O materials during their ascent to the surface or storage in the shallow magma reservoirs. The increase of zircon δ 18 O values towards eruptions in both the MTT and YTT suggests that the two eruptions may be accompanied by roof collapse that added high-δ 18 O materials to the magma. Thus, assimilation of high-δ 18 O crustal materials could be a possible trigger for the MTT and YTT eruptions. • Toba volcanic rocks were derived from an isotopically enriched and heterogenous mantle source with significant crustal contamination. • Hf-O isotopes of MTT zircon crystals exhibit characteristics of shallow-level crustal contamination. • The YTT magma reservoir was contaminated by both high- and low-δ 18 O crustal materials. • Assimilation of high-δ 18 O materials by roof collapse could be a likely eruption trigger for the MTT and YTT eruptions.

Mantle contribution to the generation of the giant Jinduicheng porphyry Mo deposit, Central China: New insights from combined in-situ element and isotope compositions of zircon and apatite

Identifying crust–mantle interaction is important for understanding the genesis of granite-hosted mineral deposits in post-collisional or intracontinental settings. We have used combined zircon-apatite trace element compositions, zircon HfO isotopes and apatite SrNd isotopes, which were all acquired by in-situ techniques, to evaluate the mantle contribution to the formation of a giant porphyry Mo deposit, the Jinduicheng deposit in the East Qinling–Dabie orogenic belt, Central China. Zircons from the host granites yielded a UPb age of ∼139 Ma, suggesting a post-collisional setting for the ore-related intrusion. Most magmatic zircons from the granites have Ti-in-zircon temperatures lower than 830 °C, moderate Zr/Hf ratios (25–55), and mantle-like δ18O values (peaking at ∼5.6‰), similar to typical I-type granites worldwide. The magmatic zircons have variable εHf(t) values (−26.7 to −7.2) and Ti-in-zircon temperatures (646–894 °C, peaking at ∼740 °C). The coexisting igneous apatites have initial 87Sr/86Sr ratios of 0.70694–0.71027, and variable εNd(t) values (−16.0 to −9.3), Sr contents (132–663 ppm), and Eu/Eu* values (0.12–0.47). The Sr–Nd–Hf isotopes of the apatites and zircons, along with the positive correlations between apatite Sr contents, Eu/Eu* values, and εNd(t) values, a positive correlation between Ti-in-zircon temperatures and zircon εHf(t) values, as well as mixing modeling using SrNd isotopes, suggest that at least two end-member melts were involved in the formation of the host granites: one is the ancient lower crust-derived melt, and the other is the metasomatized lithospheric mantle-derived melt, which have relatively enriched and depleted Sr–Nd–Hf isotopic compositions, respectively. We suggest that the post-collisional lithospheric thinning, asthenospheric upwelling and underplating of the mantle-derived mafic magmas may have triggered the crustal melting, magma mixing, and generation of the host granites of the Jinduicheng deposit. We postulate that, besides the heat, the metasomatized lithospheric mantle-derived magmas likely supplied additional volatiles (e.g., Cl, S), facilitating the porphyry Mo formation. Our study highlights that, combined in-situ element and isotope compositions of accessory minerals can provide multidimensional insights into petrogenetic tracing, and enhance the genetic interpretations of granites and related mineral deposits.

Effects of Particle Abrasion Media and Pressure on Flexural Strength and Bond Strength of Zirconia.

To compare the effects of particle abrasion medium and pressure on shear bond strength and biaxial flexural strength of three generations of zirconia (Lava Frame, Lava Plus, and Lava Esthetic) with the goal of optimizing the bond to zirconia. 280 discs (14 mm diameter; 1 mm thickness) of each zirconia were milled and sintered. Specimens of each material were randomly distributed into 14 groups (n=20); half were tested for shear bond strength and half were tested for biaxial flexural strength. The specimens were particle abraded on one surface by 2 different media (50 μm alumina particles or 50 μm glass beads) for 10 seconds at three different pressures (15, 30, and 45 psi or 0.1, 0.2, 0.3 MPa). Untreated specimens served as positive control. A tube (1.50 mm diameter) filled with dual cured resin cement (Panavia SA) was placed onto the surface and light cured. Specimens were stored in water (37°C for 24 hours) and shear bond strength was measured in a universal testing machine (Instron). Biaxial flexural strength of each specimen was measured according to ISO 6872. Shear bond strength and biaxial flexural strength were compared individually with a 2-way analysis of variance (ANOVA) for factors surface treatment and zirconia composition. Significant differences were seen between surface treatments (p<0.01), zirconia composition (p<0.01) and their interaction (p<0.01) for both bond strength and flexural strength. With alumina particle abrasion, higher pressure produced higher bonds for Lava Frame and Lava Plus zirconia while the bond of Lava Esthetic declined with increased pressure. Higher pressure (>0.2 MPa or 30 psi) with alumina decreased biaxial flexural strength with Lava Esthetic zirconia. Particle abrasion with alumina produced a significantly better combination of bond strength while maintaining biaxial strength of three zirconia materials than particle abrasion with glass beads. The bond strength also depended upon the pressure of particle abrasion and the generation of zirconia used.

Zircon texture and composition fingerprint HREE enrichment in muscovite granite bedrock of the Dabu ion-adsorption REE deposit, South China

More than 90% of the global heavy rare earth elements (HREE) supply is currently from the ion-adsorption REE deposits in South China. However, the mechanism of HREE enrichment in granite bedrock of REE mineralized weathering crusts remains poorly understood. In this study, we present a comprehensive investigation on zircon texture and composition as a proxy to unravel the magmatic-hydrothermal processes which resulted in HREE enrichment of the Dabu muscovite granites. Our results show that zircon in the Dabu muscovite granites can be classified into three types based on morphology, internal structure and chemical compositions. The early-magmatic zircon grains (ZrnI) are prismatic crystals with bright oscillatory zoning, and crystallized early in the granitic magma. The late-magmatic zircon grains (Zrn-II) occur as murky euhedral or subhedral crystals or as overgrowth on ZrnI, and crystallized from a volatile-enriched residual melt in the late magmatic stage. The hydrothermal zircon (Zrn-III) is anhedral without oscillatory zoning, possibly formed via intense hydrothermal alteration of Zrn-II in the hydrothermal stage. Raman spectra show a decrease in degree of crystallinity from Zrn-I to Zrn-III. In-situ compositional and isotopic analyses suggest that zircon geochemistry is a good proxy for the magmatic-hydrothermal processes of the host granite. Zircon UPb dating yields similar ages of 155.3 ± 1.4 Ma (2σ) and 154.1 ± 1.0 Ma (2σ) for Zrn-I and Zrn-II, respectively. The decrease of Zr/Hf from Zrn-I to Zrn-III indicates that the Dabu muscovite granites underwent magmatic to hydrothermal evolution. Furthermore, the decreasing δ18O values of Zrn-I to Zrn-III suggest the increasing involvement of meteoric water in the fluids. Significantly, compared with Zrn-I and Zrn-II, Zrn-III has the highest U, Hf and REE, in particular HREE. The LREE/HREE ratios decrease with the increase of REE contents and the decrease of Zr/Hf ratios from early to late zircon of the granite bedrock of ion-adsorption HREE deposits, which is significantly different from those of carbonatite-alkaline related REE deposits. The significant increase of HREE concentrations in early to late zircon should be ascribed to the introduction of HREE-rich fluids during magma evolution. Therefore, we propose that the HREE-rich fluids from magma exsolution metasomatized the granites to achieve further enrichment of HREE, which is an important prerequisite for the formation of ion-adsorption HREE deposits. Accordingly, we argue that zircon composition can be used as a chemical indicator for the REE behaviors in magmatic-hydrothermal systems that are vital to the formation of REE deposits.

Petrogenesis and Metallogenesis of Granitoids in the Yangla Cu-W Polymetallic Deposit, Southwest China: Evidence from Zircon Trace Elements and Hf Isotope

Magmatic zircon tends to present characteristic trends in trace element compositions in response to magma petrogenesis and metallogenesis, such that zircon may provide a window into melt evolution not accessible by whole rock chemistry. The Yangla large Cu deposit is located in the central part of the Jinshajiang Suture Zone, southwest China, constrained between the Jinshajiang and Yangla Faults. In this study, the trace elements and hafnium isotopic compositions of zircons from quartz diorite were studied. Previous published relevant data of Yangla granitoid plutons (i.e., dioritic enclave, granodiorite, and quartz monzonite porphyry) also have been systematically cited and discussed. The result shows that the crystallization temperature and two-stage Hf mode ages (tCDM; the age of the source rocks for the magmas) gradually increased while the oxygen fugacity (fO2) and εHf(t) values gradually decreased, corresponding to the diorite enclave (~232 Ma), through granodiorite (~208 Ma) and quartz monzonite porphyry (~202 Ma), and to quartz diorite (~195 Ma). It is suggested that four plutons were from the same three-component mixing of upper crust + lower crust + mantle magmas, while the upper crustal metasediments ratios were gradually increased from the early to late stage. The increasing upper crust inputs resulted in higher melting temperatures and compositions of the initial magma. All melts experienced distinct fractional crystallization of apatite, titanite, and amphibole, and the later granite melts experienced higher assimilation and fractional crystallization degrees than the early ones in the evolution processes four stages of intrusive rocks. These Yangla granitoids are the products of large-scale acid magmatic emplacement activities in the Triassic-early Jurassic and have a good metallogenic potential of the Cu-W polymetallic deposit.

Crustal evolution and tectonomagmatic history of the Indian Shield at the periphery of supercontinents

River sand detrital zircons from several rivers flowing through the Peninsular Indian cratons were analyzed for U-Pb, Lu-Hf, and O isotopes to characterize the Precambrian crustal evolution of the Indian Shield and to constrain its role in the early supercontinent cycles. Analyzed river sand zircon samples exhibit a prominent age grouping at 2.7–2.4 Ga and additional peaks at 1.8–1.7 Ga, 1.0–0.8 Ga, and 0.6–0.5 Ga. The time-related Hf and O isotope trends of the Indian zircons display a slight offset from the global trends. The age peaks and distinct Hf-O isotopic compositions of the Indian zircons also lack coherence with the global patterns associated with supercontinent cycles, implying a discrete crustal evolutionary history for the Indian Shield. Their contrasting εHf-age trajectories indicate that the Indian Shield was accreted to the Columbia/Nuna supercontinental framework through a collision event that postdated the 2.1–1.8 Ga global-scale orogeny, and was part of a long-lived subduction system along the margin of Rodinia. This implies that the Indian Shield occupied a peripheral paleo-position during the assembly of the two Precambrian supercontinents. The ca. 2.6–2.4 Ga Indian river sand zircons have remarkably low δ18O values that are distinct from the global zircon O isotopic record. This period coincides with the fragmentation of the Archean supercraton and the flaring-up of a subaerial Large Igneous Province that facilitated the generation of 18O-depleted magmas. Depending on whether the 2.6–2.4 Ga zircons with low δ18O values (<4.7 ‰) are considered or not, approximately 2.77 ‰ or 1.78 ‰ rise in the zircon δ18O values occurred between ca. 2.4 Ga and ca. 1.87 Ga (decoupled from zircon Lu-Hf isotopes), further suggesting that the fine-grained sediments were enriched in 18O after the Great Oxidation Event. These high δ18O sediments were subsequently incorporated into the magmatic systems resulting in elevated δ18O in the zircons crystallizing from such melts. Nevertheless, a ca. 0.9 Ga peak of >10 ‰ in δ18O system was followed by a pronounced δ18O drop at ca. 0.759 Ga, suggesting that δ18O of recycled sedimentary reservoirs was not the only controlling factor for zircon δ18O characteristics. Variations in the Hf-O data for Indian and global zircons could be attributed to the initiation of the supercontinent cycle at ca. 2.0 Ga. A significant volume of the juvenile crust was added during the 3.0–2.7 Ga mafic magmatism in the Indian Shield, as underlined by the Hf model ages of all the zircon grains and those with mantle-like δ18O signatures. A gradual addition of continental crust during ca. 3.6 Ga to 3.1 Ga can also be deduced, with the oldest crust being derived from the mantle at ca. 4.4 Ga.

Ediacaran mafic magmatism recorded in Cambrian eclogites of the Ross orogen, Antarctica: Implications for the Neoproterozoic rifting episodes along the Pacific‐Gondwana margin

AbstractWe report the first finding of Ediacaran mafic magmatism in northern Victoria Land of the Ross orogen, Antarctica, based on ca. 600–590 Ma magmatic zircon cores in Cambrian eclogites. The mafic magmatism could be either linked to ca. 615–590 Ma incipient convergent margin magmatism in central segment of the Ross orogen, or ca. 600–580 Ma continental rift‐related volcanism widespread in eastern Australia. The latter is preferred based on the trace‐element compositions distinctive from those of arc‐related basalts and the depleted mantle‐like Hf isotopic compositions of zircon. Our results suggest dual rifting episodes during both the Ediacaran and Cryogenian (ca. 670–650 Ma) in the East Antarctic margin, correlative with those in eastern Australia. A spatial distribution of coeval rifting and subduction along the Ediacaran margin of East Antarctica is readily accounted for by rift inheritance; the upper‐ and lower‐plate geometry resulting from detachment and transform faulting.

Temperature and Hf-O isotope correlations of young erupted zircons from Tengchong (SE Tibet): Assimilation fractional crystallization during monotonic cooling

Young zircons from crystal-poor volcanic rocks provide the best samples for the investigations of pre-eruption magmatic processes and for testing a possible relationship between zircon Eu anomalies and crustal thickness. We report trace element chemistry and Hf-O isotope compositions of young zircons from 3 Holocene volcanoes in the Tengchong volcanic field, SE Tibet, in order to provide insights into magma evolution processes and conditions for high-K calc-alkaline volcanic rocks in a post-collisional setting. As decreasing zircon Ti content and falling temperature, zircon Hf content and Yb/Sm increase whereas zircon Eu anomaly and Th/U decrease, indicating fractional crystallization of plagioclase and zircon during magma cooling. More importantly, zircon Hf isotope ratio (εHf values) increases with decreasing zircon Ti content and falling temperature (T), suggesting gradually increasing incorporation of relatively high εHf juvenile materials in the crystallizing zircons during magma evolution. Negative correlations between zircon εHf and zircon δ18O also support open-system magma evolution. Our data suggest fractional crystallization of a magma with simultaneous contamination by high εHf and low δ 18O juvenile (immature) crustal materials during monotonic cooling after zircon saturation. The low-T, high-εHf and low- δ 18O zircons may indicate the involvement of the early Cretaceous juvenile granitic country rocks during shallow magma evolution. Average Eu anomalies in zircons from young Tengchong lavas yield crustal thickness of 40.7 ± 6.8 km, consistent with present crustal thickness (42.5 km) determined by geophysical methods.

Pulsed laser ablation of cutting edge geometries in alumina and zirconia composites at 200 fs and 2 ps

In this study, the feasibility of lasermachining cutting edges into mixed oxide ceramics such as alumina toughened zirconia (ATZ) and zirconia toughened alumina (ZTA) is evaluated. A simplified standard wedge geometry is machined into cylindrical samples by combining orthogonal and quasi-tangential laser machining strategies. For the experiments a laser source emitting a wavelength of 515 nm is applied and the pulse duration is varied between 0.2 and 2 ps. As target parameters the cutting edge radius and Sa value of the rake face are analyzed. The heat affected zone is analyzed by FIB SEM. An edge radius of 6.7±1.6μm at an Sa value of 0.115μm in the case of ZTA and an edge radius of 4.9±0.3μm at an Sa value of 0.125μm in the case of ATZ can be achieved. The results are promising for the application of laser ablation towards the manufacturing of cutting edges in oxide ceramics such as ATZ and ZTA.