This study investigated the carbonization of mixture of agricultural by-products (corn cob, cotton shell and rice straw) from Tchad in view to produce charcoal as alternative environmentally friendly source of energy. The structural analysis of the selected biomasses was assessed. The best mixture was identified by the mean of mixture design methodology. The structural analysis (cellulose, hemicellulose and protein) was different from one biomass to another, predicting the possibility to increase charcoal yield by suitable mixture design before carbonization. The result also revealed that taking individually, charcoal yields were 43.56%, 37.20% and 30.07% respectively for rice straw, cotton shell and corn cob. For the optimised mixture of biomasses, the validation conditions presented an adjusted R2 of 98%, a mean absolute deviation (AAD) of 3%, a bias factor of 1.00 and an accuracy factor of 1.04, within the interval to validate. The high charcoal yield was 49.70% and was obtained for the mixture made from19.0 wt.% of corn cob, 68.7 wt.% of rice straw and 12.3 wt.% of cotton shell. This result shows that the mixture of rice straw, cotton shell and corn cob increased the charcoal yield by approximately 6.14%. This percentage is however lower than the 10% increase often observed for hydrothermal carbonization, possibly due to carbonization conditions. Therefore, the mixture of corn cob, cotton shell and rice straw before carbonization process provide a sustainable pathway for the conversion of biomass into solid products with improved charcoal yield compared to those produced by carbonizing the feedstocks separately.
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