This paper presents a hybrid Model Predictive Control (hMPC) approach to improve Electric Vehicle (EV) stability when cornering or in high-risk driving conditions. By using approximations of tire force characteristics, the EV system proposed in this study is considered as a Piecewise Affine (PWA) system which is a class of Hybrid Dynamical Systems (HDSs). First, a hybrid modeling of the studied system is developed within the PWA framework. Then, the synthesis of an explicit hybrid MPC law, based on the integration of the Active Front-wheel Steering control method (AFS) and Direct Yaw moment Control method (DYC), can be established. The purpose of the PWA-MPC is to force the yaw rate and sideslip angle of the EV system to follow the given references to guarantee lateral stability. The calculation of the control laws of this proposed approach is performed offline using multiparametric programming. Finally, this paper investigates the effectiveness of the designed controller by performing a set of simulations to analyze the efficiency and robustness of the proposed approach. A comparative study is addressed in this work to demonstrate the efficiency of the proposed hybrid MPC controller compared to the conventional MPC approach which considers the linear model of the system. Another simulations are carried out to assess the robustness of the proposed control, important disturbances and uncertainties were incorporated such as the change of the additional mass, the change of terrain and the high velocity. The simulation results show that the PWA EV system model with the designed controller is able to ensure lateral stability by keeping the sideslip angle and yaw rate tracking the ideal values.