We have demonstrated the use of electron spin resonance (ESR) spectroscopy to observe the influence of high-temperature annealing in an oxidizing atmosphere on Cr3+ ion concentration changes in an epitaxial Cr,Mg:YAG saturable absorber. For this purpose, a set of samples of epitaxial Cr,Mg:YAG/YAG structures differing in both the concentration of Cr and Mg ions and the concentrations ratio of these ions have been synthesized using liquid phase epitaxy. The X-ray diffraction analysis and optical transmission spectra measurements were performed to characterize the obtained layers. The usefulness of the ESR technique for monitoring certain high-temperature induced changes in epitaxial Cr,Mg:YAG absorber has been verified.
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